While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …

The synthesis, characterization, and protonation of [Fe2 (CO) 6 {(μ-SCH2) 2 (Et) P═ O}](1)
using the moderately strong acid CF3CO2H (p K aMeCN= 12.7) are reported. Digital …

Synthetic models of the active site of [FeFe]-hydrogenase containing naphthalene
monoimide (NMI) of peri-substituted dichalcogenides as bridging linkers have been …

The effect of the nature of the dithiolato ligand on the physical and electrochemical
properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant …

The synthetic models of the active site of an [FeFe]-hydrogenase containing a Sn atom in the
bridgehead of the diselenato ligand, namely [Fe2 (CO) 6 {μ-(SeCH2Se) SnMe2}], 3 and [Fe2 …

In this work, a series of DFT and DFT‐D methods is combined with double‐ζ basis sets to
benchmark their performance in predicting the structures of five newly synthesized …

The nature of the bridging dithiolate has an important role on tuning the physical and
electrochemical properties of the synthetic H-cluster mimics of [FeFe]-hydrogenase and still …

In this report, the influence of the substitution decoration in ferrocenyl selenophen-2-yl
thioketone (1) and ferrocenyl furan-2-yl thioketone (2) utilized as a proligand in …

In this research work we present the reaction of the precursor complexes [Fe 2 (CO) 6 {μ-
(SeCH 2) 2 CMeR}](R= H (1) or Me (2)) with monophosphine/phosphane ligands, PPh 3 and …