Transition metal‐catalyzed enantioselective functionalization of C− H bond, the most
abundant functionality in organic molecules, has emerged as an expedient synthetic …

Atropisomeric molecules have found proven applications and have shown promising
potential in chemistry and medicine. The design of N‐heterocyclic carbene (NHC) catalyzed …

An enantioselective C− H arylation of phosphine oxides with o‐quinone diazides catalyzed
by an iridium (III) complex bearing an atropchiral cyclopentadienyl (Cpx) ligand and …

Atroposelective synthesis of axially chiral biaryls by palladium‐catalyzed C− H olefination,
using tert‐leucine as an inexpensive, catalytic, and transient chiral auxiliary, has been …

Does the dehydrogenative coupling of aromatic compounds mediated by AlCl3 at high
temperatures and also by FeCl3, MoCl5, PIFA, or K3 [Fe (CN) 6] at room temperature …

The first catalytic asymmetric construction of 3, 3′‐bisindole skeletons bearing both axial
and central chirality has been established by organocatalytic asymmetric addition reactions …

Axially chiral open‐chain olefins represent an underexplored class of chiral platform. In this
report, two classes of tetrasubstituted axially chiral acyclic olefins have been accessed in …

Cyclopentadienyl (Cp) ligands enable efficient steering of various transition‐metal‐
catalyzed transformations, in particular enantioselective C− H activation. Currently only few …

The first enantioselective construction of a new class of axially chiral naphthyl‐indole
skeletons has been established by organocatalytic asymmetric coupling reactions of 2 …

The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …