Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Magnetic anisotropy is the property that confers to the spin a preferred direction that could
be not aligned with an external magnetic field. Molecules that exhibit a high degree of …

This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Single-molecule magnets (SMMs) have attracted increasing attention in recent years due to
the potentially applicable in high-density information storage and spintronic devices. There …

Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

The widely accepted assumption that the development of more efficient single molecule
magnets must involve ever higher total spin values has so far driven synthetic efforts towards …

Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

Polyoxometalates (POMs), anionic oxide clusters of the early transition metals,[1] represent
a vast class of inorganic materials with a virtually unmatched range of properties applicable …