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Selected Copper‐Based Reactions for C− N, C− O, C− S, and C− C Bond Formation
Metal‐catalyzed cross‐coupling reactions belong to the most important transformations in
organic synthesis. Copper catalysis has received great attention owing to the low toxicity …
organic synthesis. Copper catalysis has received great attention owing to the low toxicity …
Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis
Natural product synthesis is a highly demanding field in constant need of efficient
transformations that allow either straightforward, scalable, and high-yielding preparation of …
transformations that allow either straightforward, scalable, and high-yielding preparation of …
Cu-mediated Ullmann-type cross-coupling and industrial applications in route design, process development, and scale-up of pharmaceutical and agrochemical …
Q Yang, Y Zhao, D Ma - Organic Process Research & …, 2022 - ACS Publications
Cu-mediated Ullmann-type cross-coupling has experienced significant advances over the
last century since the seminal publication by Ullmann in 1901. These advances have …
last century since the seminal publication by Ullmann in 1901. These advances have …
Catalytic C C, C N, and C O Ullmann‐Type Coupling Reactions
Copper‐catalyzed Ullmann condensations are key reactions for the formation of carbon–
heteroatom and carbon–carbon bonds in organic synthesis. These reactions can lead to …
heteroatom and carbon–carbon bonds in organic synthesis. These reactions can lead to …
Copper-promoted carbon-heteroatom bond cross-coupling with boronic acids and derivatives
JX Qiao, PYS Lam - Synthesis, 2011 - thieme-connect.com
The discovery of the copper-promoted Chan-Lam coupling reaction with boronic acids more
than ten years ago has greatly advanced the carbon-heteroatom cross-coupling chemistry …
than ten years ago has greatly advanced the carbon-heteroatom cross-coupling chemistry …
Recent advances in the synthesis of (hetero) aryl-substituted heteroarenes via transition metal-catalysed direct (hetero) arylation of heteroarene C–H bonds with aryl …
(Hetero) aryl groups directly connected by single Csp2–Csp2 bonds to heteroaryl moieties
are present as core structures in many biologically active compounds, 1 naturally-occurring …
are present as core structures in many biologically active compounds, 1 naturally-occurring …
The chosen few: parallel library reaction methodologies for drug discovery
AW Dombrowski, AL Aguirre, A Shrestha… - The Journal of …, 2021 - ACS Publications
Parallel library synthesis is an important tool for drug discovery because it enables the
synthesis of closely related analogues in parallel via robust and general synthetic …
synthesis of closely related analogues in parallel via robust and general synthetic …
Bayesian optimization as a sustainable strategy for early-stage process development? A case study of Cu-catalyzed C–N coupling of sterically hindered pyrazines
E Braconi, E Godineau - ACS Sustainable Chemistry & …, 2023 - ACS Publications
Bayesian optimization is a powerful machine learning technique that is particularly well-
suited for optimizing chemical reactions in the early stages of process development. It can …
suited for optimizing chemical reactions in the early stages of process development. It can …
Alternative Mechanistic Explanation for Ligand-Dependent Selectivities in Copper-Catalyzed N- and O-Arylation Reactions
HZ Yu, YY Jiang, Y Fu, L Liu - Journal of the American Chemical …, 2010 - ACS Publications
The ligand-dependent selectivities in Ullmann-type reactions of amino alcohols with
iodobenzene by β-diketone-and 1, 10-phenanthroline-ligated CuI complexes were recently …
iodobenzene by β-diketone-and 1, 10-phenanthroline-ligated CuI complexes were recently …
Cu-catalyzed arylation of phenols: synthesis of sterically hindered and heteroaryl diaryl ethers
Cu-catalyzed O-arylation of phenols with aryl iodides and bromides can be performed under
mild condition in DMSO/K3PO4 with use of picolinic acid as the ligand for copper. This …
mild condition in DMSO/K3PO4 with use of picolinic acid as the ligand for copper. This …