Stereochemical and structural characteristics of single-and double-site Pd (II)–N-heterocyclic carbene complexes: Promising catalysts in organic syntheses ranging …
This review discusses the principles underlying the design, synthesis, and catalytic
application of mono-and binuclear Pd (II)–N-heterocyclic carbene (NHC) complexes. The …
application of mono-and binuclear Pd (II)–N-heterocyclic carbene (NHC) complexes. The …
Trans-chelating diphosphines, the elusive ligands!
The development of chelating diphosphine ligands has been a prolific research area for
several decades, but quite surprisingly, from the plethora of diphosphines that are currently …
several decades, but quite surprisingly, from the plethora of diphosphines that are currently …
Metal-free perfluoroarylation by visible light photoredox catalysis
Visible light and eosin Y catalyze the direct arylation of simple arenes with fluorinated aryl
bromides by a photoredox process. The reaction scope is broad in fluorinated compounds …
bromides by a photoredox process. The reaction scope is broad in fluorinated compounds …
Microwave-promoted Suzuki–Miyaura cross-coupling of aryl halides with phenylboronic acid under aerobic conditions catalyzed by a new palladium complex with a …
A new air-and moisture-stable palladium complex with salicylaldehyde N (4)-
hexamethyleneiminylthiosemicarbazone has been synthesized. According to its crystal …
hexamethyleneiminylthiosemicarbazone has been synthesized. According to its crystal …
Recent Developments in Radical‐Mediated Transformations of Organohalides
In recent years, radical‐mediated transformations of organohalides, a class of powerful
chemical transformations, have become an important field at the forefront of organic …
chemical transformations, have become an important field at the forefront of organic …
Palladium complexes bearing novel strongly bent trans-spanning diphosphine ligands: Synthesis, characterization, and catalytic activity
O Grossman, C Azerraf, D Gelman - Organometallics, 2006 - ACS Publications
The new air-stable chelating diphosphine ligands 1, 8-bis (diisopropylphosphino) triptycene
(2) and 1-(diisopropylphosphino)-8-(diphenylphosphino) triptycene (3) were synthesized in …
(2) and 1-(diisopropylphosphino)-8-(diphenylphosphino) triptycene (3) were synthesized in …
Trans-chelating ligands in palladium-catalyzed carbonylative coupling and methoxycarbonylation of aryl halides
L Kaganovsky, D Gelman, K Rueck-Braun - Journal of Organometallic …, 2010 - Elsevier
The manuscript describes the use of a trans-chelated palladium complex derived from 1, 8-
bis-(4-(diphenylphosphino) phenyl) anthracene (1) and p-TolPdI (TMEDA) as a precatalyst …
bis-(4-(diphenylphosphino) phenyl) anthracene (1) and p-TolPdI (TMEDA) as a precatalyst …
A DFT comparison of the neutral and cationic Heck pathways
C Bäcktorp, PO Norrby - Dalton Transactions, 2011 - pubs.rsc.org
The two distinct mechanistic pathways of the Heck reaction, cationic and neutral, are
characterized computationally using DFT calculations with corrections for solvation and …
characterized computationally using DFT calculations with corrections for solvation and …
Palladium complexes with stabilized germylene and stannylene ligands
MM Kireenko, KV Zaitsev, YF Oprunenko… - Dalton …, 2013 - pubs.rsc.org
The syntheses of novel Pd complexes with germylene and stannylene ligands are
reported.[MeN (CH2CH2NC6F5) 2Sn] 4Pd (2) and [MeN (CH2CPh2O)(CH2CH2O) Ge] 4Pd …
reported.[MeN (CH2CH2NC6F5) 2Sn] 4Pd (2) and [MeN (CH2CPh2O)(CH2CH2O) Ge] 4Pd …
Four-coordinate Pd (II) complexes containing non-symmetric phosphorus ylides: Synthesis, characterization, and catalytic behavior towards Suzuki reaction
In this paper it is reported the synthesis of the complexes of the type {[Ph2PCH2PPh2CHC
(O) R] PdCl2}(R= 4′-biphenyl (1), OCH2Ph (2), 4-methylphenyl (3), 2-naphtyl (4), 2, 4 …
(O) R] PdCl2}(R= 4′-biphenyl (1), OCH2Ph (2), 4-methylphenyl (3), 2-naphtyl (4), 2, 4 …