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Main group bimetallic partnerships for cooperative catalysis
Over the past decade s-block metal catalysis has undergone a transformation from being an
esoteric curiosity to a well-established and consolidated field towards sustainable synthesis …
esoteric curiosity to a well-established and consolidated field towards sustainable synthesis …
Assembling heterometals through oxygen: an efficient way to design homogeneous catalysts
Assembling a molecule containing two metal centers with entirely different chemical
properties remains a synthetic challenge. One of the major motivations for this chemistry is …
properties remains a synthetic challenge. One of the major motivations for this chemistry is …
Aluminum-Containing Heterobimetallic Complexes as Versatile Platforms for Homogeneous Catalysis
Within the broader area of heterobimetallic catalysis, Al/M compounds (M= any metal) are
promising for the design and execution of catalytic manifolds. This Perspective reviews …
promising for the design and execution of catalytic manifolds. This Perspective reviews …
β‐Diketonate, β‐Ketoiminate, and β‐Diiminate Complexes of Difluoroboron
FP Macedo, C Gwengo, SV Lindeman, MD Smith… - 2008 - Wiley Online Library
A series of β‐diketonate, keto (aryl) iminato, and β‐bis (aryl) iminato complexes of
difluoroboron, twenty in total, have been prepared to assess the impact of chelate ring and …
difluoroboron, twenty in total, have been prepared to assess the impact of chelate ring and …
Organoaluminum species in homogeneous polymerization catalysis
This chapter highlights the most recent and representative results on the use of
organoaluminum compounds in polymerization catalysis with a special emphasis on …
organoaluminum compounds in polymerization catalysis with a special emphasis on …
Aluminum complexes with redox-active formazanate ligand: Synthesis, characterization, and reduction chemistry
The synthesis of aluminum complexes with redox-active formazanate ligands is described.
Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two …
Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two …
Studies of the ligand effect on the synthesis of dialuminoxanes by various β-diketiminato ligands
Reactions of LH (L= HC [C (Me) N (2, 6-Me2C6H3)] 2) with Me n AlCl3–n in diethyl ether
afforded the adducts LH· AlMe n (Cl) 3–n (n= 2, 3; 1, 4; 0, 5) in good yields. Treatment of 3 at …
afforded the adducts LH· AlMe n (Cl) 3–n (n= 2, 3; 1, 4; 0, 5) in good yields. Treatment of 3 at …
Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide …
The hydrolysis reaction between Brønsted basic organometallic or metal–amide reagents
with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled …
with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled …
1, 4-Diphosphorinane Synthesis at a Cationic Aluminum (III) Center
Lewis acidic group 13 cations are useful mediators of small-molecule and catalytic reactivity
alike. Previous work has elaborated on the use of bulky β-diketiminate Al (III) cations for the …
alike. Previous work has elaborated on the use of bulky β-diketiminate Al (III) cations for the …
Synthesis and structural study on organoantimony (III) and organobismuth (III) hydroxides containing an NCN pincer type ligand
A Fridrichová, T Svoboda, R Jambor… - …, 2009 - ACS Publications
The reactions of the dimeric organoantimony (III) oxide [LSbO] 2 (3), containing the NCN
chelating ligand L (L= C6H3-2, 6-(CH2NMe2) 2) with trifluoroacetic acid and …
chelating ligand L (L= C6H3-2, 6-(CH2NMe2) 2) with trifluoroacetic acid and …