Over the past decade s-block metal catalysis has undergone a transformation from being an
esoteric curiosity to a well-established and consolidated field towards sustainable synthesis …

Assembling a molecule containing two metal centers with entirely different chemical
properties remains a synthetic challenge. One of the major motivations for this chemistry is …

Within the broader area of heterobimetallic catalysis, Al/M compounds (M= any metal) are
promising for the design and execution of catalytic manifolds. This Perspective reviews …

A series of β‐diketonate, keto (aryl) iminato, and β‐bis (aryl) iminato complexes of
difluoroboron, twenty in total, have been prepared to assess the impact of chelate ring and …

This chapter highlights the most recent and representative results on the use of
organoaluminum compounds in polymerization catalysis with a special emphasis on …

The synthesis of aluminum complexes with redox-active formazanate ligands is described.
Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two …

Reactions of LH (L= HC [C (Me) N (2, 6-Me2C6H3)] 2) with Me n AlCl3–n in diethyl ether
afforded the adducts LH· AlMe n (Cl) 3–n (n= 2, 3; 1, 4; 0, 5) in good yields. Treatment of 3 at …

The hydrolysis reaction between Brønsted basic organometallic or metal–amide reagents
with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled …

The four-coordinated bis (benzyl sulfide) complex L 1 Al (SCH 2 Ph) 2 (1) was synthesized
in good yield by reacting one equivalent of L 1 AlH 2 (L 1= HC (CMeNAr) 2, Ar= 2, 4, 6-Me 3 …

Lewis acidic group 13 cations are useful mediators of small-molecule and catalytic reactivity
alike. Previous work has elaborated on the use of bulky β-diketiminate Al (III) cations for the …