Thin films of block copolymer
MW Matsen - The Journal of chemical physics, 1997 - pubs.aip.org
We develop a numerical method for examining complex morphologies in thin films of block
copolymer using self-consistent field theory. Applying the method to confined films of …
copolymer using self-consistent field theory. Applying the method to confined films of …
Conformationally asymmetric block copolymers
The standard parameters controlling AB diblock copolymer phase behavior are χN and fA,
where χ is an A‐B segment interaction parameter, N is the overall degree of polymerization …
where χ is an A‐B segment interaction parameter, N is the overall degree of polymerization …
Theoretical simulations of nanostructures self-assembled from copolymer systems
Copolymer systems can self-assemble into diverse nanostructures, which have gained
significant attention because of their diverse and expanding range of practical applications …
significant attention because of their diverse and expanding range of practical applications …
Stability of the perforated layer (PL) phase in diblock copolymer melts
DA Hajduk, H Takenouchi, MA Hillmyer… - …, 1997 - ACS Publications
We reexamine the stability of hexagonally modulated layer (HML) and hexagonally
perforated layer (HPL) morphologies in a number of block copolymer systems of low to …
perforated layer (HPL) morphologies in a number of block copolymer systems of low to …
Transformations to and from the Gyroid Phase in a Diblock Copolymer
Simultaneous small-angle scattering and in situ dynamic mechanical measurements offer an
excellent opportunity to relate the macroscopic dynamical mechanical response of block …
excellent opportunity to relate the macroscopic dynamical mechanical response of block …
Cell dynamics simulations of block copolymers
IW Hamley - Macromolecular theory and simulations, 2000 - Wiley Online Library
Cell dynamics simulations are a powerful tool to simulate kinetic processes in phase
separating systems. Here we review the technique and its application to block copolymers …
separating systems. Here we review the technique and its application to block copolymers …
Stability of ordered phases in diblock copolymer melts
The stability of the diblock copolymer ordered phases is investigated by means of a novel
theory of anisotropic composition fluctuations. The analogy between a polymer chain in a …
theory of anisotropic composition fluctuations. The analogy between a polymer chain in a …
Kinetic Pathway of the Order–Order Transition from Hexagonally Packed Cylinder to Hexagonally Perforated Layer in Polystyrene-block-Poly(2-vinylpyridine) Using …
The kinetic pathway of the order–order transition (OOT) from a hexagonally packed cylinder
(HEX) to a hexagonally perforated layer (HPL) phase in polystyrene-block-poly (2 …
(HEX) to a hexagonally perforated layer (HPL) phase in polystyrene-block-poly (2 …
Kinetics and mechanisms for the cylinder-to-gyroid transition in a block copolymer solution
CY Wang, TP Lodge - Macromolecules, 2002 - ACS Publications
The cylinder-to-gyroid transition in a block copolymer solution has been studied using a
combination of rheology and small-angle X-ray scattering (SAXS). A poly (styrene-b …
combination of rheology and small-angle X-ray scattering (SAXS). A poly (styrene-b …
Epitaxial Transitions in Complex Polymeric Liquids
MW Matsen - Physical review letters, 1998 - APS
The topography of the Landau free energy surface of a diblock copolymer melt is found to
exhibit a low-energy pathway connecting the local minima of the cylinder (C) and gyroid (G) …
exhibit a low-energy pathway connecting the local minima of the cylinder (C) and gyroid (G) …