From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Exploiting chemistry and molecular systems for quantum information science

MR Wasielewski, MDE Forbes, NL Frank… - Nature Reviews …, 2020 - nature.com
The power of chemistry to prepare new molecules and materials has driven the quest for
new approaches to solve problems having global societal impact, such as in renewable …

[HTML][HTML] Interfacial engineering for advanced functional materials: surfaces, interfaces, and applications

AA Al-Amiery, MA Fayad, HA Hussain… - Results in …, 2024 - Elsevier
This review article comprehensively examines the diverse facets of interfacial engineering
as a transformative approach to advance functional materials. The exploration begins with …

Persistent radicals derived from N-heterocyclic carbenes for material applications

H Song, E Pietrasiak, E Lee - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Persistent radicals are potential building blocks of novel materials in many
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …

Thermally and magnetically robust triplet ground state diradical

N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Metal-free organic radical spin source

C Nicolaides, F Bazzi, E Vouros, DF Flesariu… - Nano Letters, 2023 - ACS Publications
Organic radicals have long been suggested as candidates for organic magnets and
components in organic spintronic devices. Herein, we demonstrate spin current emission …

Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical

C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …

Perspectives for polychlorinated trityl radicals

I Ratera, J Vidal-Gancedo, D Maspoch… - Journal of Materials …, 2021 - pubs.rsc.org
An organic free radical is a molecule with one or more unpaired electrons. Although most
free radicals are highly reactive, chemists have developed a few families of so-called …

Blatter radical-decorated silica as a prospective adsorbent for selective NO capture from air

AS Poryvaev, E Gjuzi, AA Yazikova… - … applied materials & …, 2023 - ACS Publications
Nitrogen oxides are adverse poisonous gases present in the atmosphere and having
detrimental effects on the human health and environment. In this work, we propose a new …