Bioinspired applications of porphyrin derivatives

JM Park, KI Hong, H Lee, WD Jang - Accounts of chemical …, 2021 - ACS Publications
Conspectus Porphyrin derivatives are ubiquitous in nature and have important biological
roles, such as in light harvesting, oxygen transport, and catalysis. Owing to their intrinsic π …

Circular dichroism sensing: strategies and applications

JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

ECD exciton chirality method today: a modern tool for determining absolute configurations

G Pescitelli - Chirality, 2022 - Wiley Online Library
The application of the exciton chirality method (ECM) to interpret electronic circular
dichroism (ECD) spectra is a well‐established and still popular approach to assign the …

Chirality gearing in an achiral cage through adaptive binding

QP Hu, H Zhou, TY Huang, YF Ao… - Journal of the …, 2022 - ACS Publications
Herein we report an adaptive, achiral trithiourea molecular cage and its conformational and
stereodynamics toward tricarboxylate anion binding. The cage was readily synthesized in …

Molecular Sensing of Chiral Carboxylic Acid Enantiomers Using CD Inductions in the Visible Light Region

JSSK Formen, E Nelson, C Wolf - The Journal of Organic …, 2025 - ACS Publications
The reaction between a chiral carboxylic acid molecule and 1, 1′-bis (diphenylphosphino)
ferrocenepalladium dichloride in the presence of a mild base generates a chiroptically active …

DFT Analysis of Dynamic, Charge, and TD-DFT Properties of Doped, Encapsulated, and Decorated First-Row Transition Metals on B12N12 Nanocage: Part 2

N De Sousa Sousa, ALP Silva, ACA Silva… - Journal of Inorganic and …, 2024 - Springer
Due to its distinctive properties and semiconducting characteristics, B12N12 has been the
subject of many studies in the field of nanoscience, as it is a promising material for various …

Chirality Interplay between the Interior and Exterior of Metal–Organic Cages

C Ma, Q Cao, L Yu, Z Ma, Q Gan - Angewandte Chemie, 2024 - Wiley Online Library
A series of metal–organic cages featuring two stereogenic elements, in terms of the twisting
of amide moieties within the ligand backbones and the rotation of diazaanthracene …

Modulation of supramolecular chirality by stepwise axial coordination in a nano-size trizinc (II) porphyrin trimer

A Dhamija, D Chandel, SP Rath - Chemical Science, 2023 - pubs.rsc.org
Herein, we report a chiral guest's triggered spring-like contraction and extension motions
coupled with unidirectional twisting in a novel flexible and 'nano-size'achiral trizinc (II) …

Surfactant-induced chirality transfer, amplification and inversion in a cucurbit [8] uril–viologen host–guest supramolecular system

H Xu, H Lu, Q Zhang, M Chen, Y Shan, TY Xu… - Journal of Materials …, 2022 - pubs.rsc.org
Chirality manipulation in supramolecules, especially in multicomponent supramolecular
structures, is crucially desired. Herein, we report a feasible approach to achieve the chirality …

Theory-Directed Ligand-Shell Engineering of Ultrasmall Gold Clusters: Remarkable Effects of Ligand Arrangement on Optical Properties

R Suzuki, Y Chen, Y Ogawa, M Enokido… - The Journal of …, 2025 - ACS Publications
Ligand-shell engineering of ultrasmall metal clusters is a burgeoning research field aiming
to develop cluster-specific properties. However, predicting these properties prior to synthesis …