Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R **, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Single-atom catalysts: a new frontier in heterogeneous catalysis

XF Yang, A Wang, B Qiao, JUN Li, J Liu… - Accounts of chemical …, 2013 - ACS Publications
Supported metal nanostructures are the most widely used type of heterogeneous catalyst in
industrial processes. The size of metal particles is a key factor in determining the …

Interface dynamics of Pd–CeO2 single-atom catalysts during CO oxidation

V Muravev, G Spezzati, YQ Su, A Parastaev… - Nature Catalysis, 2021 - nature.com
In recent years, noble metals atomically dispersed on solid oxide supports have become a
frontier of heterogeneous catalysis. In pursuit of an ultimate atom efficiency, the stability of …

[BOOK][B] CRC handbook of chemistry and physics

WM Haynes - 2016 - taylorfrancis.com
Proudly serving the scientific community for over a century, this 97th edition of the CRC
Handbook of Chemistry and Physics is an update of a classic reference, mirroring the growth …

Rational design of single‐atom site electrocatalysts: from theoretical understandings to practical applications

Y Wang, D Wang, Y Li - Advanced Materials, 2021 - Wiley Online Library
Atomically dispersed metal‐based electrocatalysts have attracted increasing attention due to
their nearly 100% atomic utilization and excellent catalytic performance. However, current …

Catalysis by supported single metal atoms

J Liu - Acs Catalysis, 2017 - ACS Publications
The recent explosive growth in research on catalysis by supported single metal atoms
proves the scientific interest in this new frontier of heterogeneous catalysis. A supported …

Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts

V Muravev, A Parastaev, Y van den Bosch, B Ligt… - Science, 2023 - science.org
The catalytic performance of heterogeneous catalysts can be tuned by modulation of the
size and structure of supported transition metals, which are typically regarded as the active …

Shape‐controlled synthesis of metal nanocrystals: simple chemistry meets complex physics?

Y **a, Y **ong, B Lim… - Angewandte Chemie …, 2009 - Wiley Online Library
Nanocrystals are fundamental to modern science and technology. Mastery over the shape of
a nanocrystal enables control of its properties and enhancement of its usefulness for a given …

Colloidal synthesis of metal nanocrystals: from asymmetrical growth to symmetry breaking

QN Nguyen, C Wang, Y Shang, A Janssen… - Chemical …, 2022 - ACS Publications
Nanocrystals offer a unique platform for tailoring the physicochemical properties of solid
materials to enhance their performances in various applications. While most work on …

The effect of coordination environment on the activity and selectivity of single-atom catalysts

Y Zhang, J Yang, R Ge, J Zhang, JM Cairney… - Coordination Chemistry …, 2022 - Elsevier
Traditional heterogeneous catalysts with noble metals as active sites only have surface-
active substances involved in the catalytic reactions, which greatly reduces the material …