State of the‐art for extrudate swell of molten polymers: from fundamental understanding at molecular scale toward optimal die design at final product scale

D Tang, FH Marchesini, L Cardon… - Macromolecular …, 2020 - Wiley Online Library
Polymer extrudate swell is a rheological phenomenon taking place after polymer melt flow
emerges the die exit of extrusion equipment, due to flow redistributions and molecular stress …

Numerical techniques for the solution of the molecular weight distribution in polymerization mechanisms, state of the art

E Saldívar‐Guerra - Macromolecular Reaction Engineering, 2020 - Wiley Online Library
The molecular weight distribution (MWD) is possibly the most important characteristic of a
polymer. Polymers derive many of their physical properties from their MWD. Therefore, since …

Climate impact of primary plastic production

N Karali, N Khanna, N Shah - 2024 - escholarship.org
Plastics show the strongest production growth of all bulk materials over the last decade. The
industry's current growth trajectory is exponential and plastic production is expected to …

Review of Monte Carlo methods for the prediction of distributed molecular and morphological polymer properties

D Meimaroglou, C Kiparissides - Industrial & Engineering …, 2014 - ACS Publications
Monte Carlo (MC) is a term quite common in the research community but, quite surprisingly,
it may possess a different meaning among researchers in different areas. This paradox is …

高压电缆交联聚乙烯绝缘的关键性能与基础问题

**盛涛, 王诗航, 杨柳青, **建英, 赵健康… - **电机工程 …, 2022 - epjournal.csee.org.cn
高压电缆是城市输电网的关键电力装备, 是海上风电输送到陆地电网, 实现新能源大规模利用的
关键电力装备. 然而, 高压电缆用交联聚乙烯绝缘料是我国高压电缆生产的“卡脖子” …

A graph theory assisted Monte Carlo algorithm for simulating the topology structure of LDPE and connection with molecular dynamics simulation

J Wang, Y Ren, Y Yang, X Fan, B Jiang… - AIChE …, 2023 - Wiley Online Library
Precise simulation of the topology structure of low‐density polyethylene (LDPE) chain is
significant for product properties research. However, the chain structure symbolization …

LDPE production in tubular reactors: comprehensive model for the prediction of the joint molecular weight-short (long) chain branching distributions

ML Dietrich, C Sarmoria, A Brandolin… - Industrial & …, 2019 - ACS Publications
Good control on molecular properties, and as a consequence on end-use properties, is very
important for low-density polyethylene (LDPE) manufacturers. However, the connection …

Efficient modeling of distributions of polymer properties using probability generating functions and parallel computing

M Asteasuain - Computers & Chemical Engineering, 2019 - Elsevier
High-fidelity models of polymer processes should include the prediction of distributions of
polymer properties, including multivariate distributions. Deterministic models with this …

Mathematical Modeling of the Molecular Weight Distribution in Low Density Polyethylene. I. Steady‐State Operation of Multizone Autoclave Reactors

B López‐Carpy, E Saldívar‐Guerra… - Macromolecular …, 2018 - Wiley Online Library
A comprehensive mathematical model and an efficient strategy for its solution are presented
to describe the complete molecular weight distribution (MWD) in the free‐radical …

Modeling Low‐Density Polyethylene (LDPE) Production in Tubular Reactors: Connecting Polymerization Conditions with Polymer Microstructure and Rheological …

ML Dietrich, C Sarmoria, A Brandolin… - Macromolecular …, 2022 - Wiley Online Library
The production of low‐density polyethylene (LDPE) in high‐pressure tubular reactors is
widely studied due to its extensive use worldwide. Reaction conditions have a crucial impact …