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Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Luminescent first-row transition metal complexes
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers
Y Liu, P Persson, V Sundstrom… - Accounts of chemical …, 2016 - ACS Publications
Conspectus The photophysics and photochemistry of transition metal complexes (TMCs)
has long been a hot field of interdisciplinary research. Rich metal-based redox processes …
has long been a hot field of interdisciplinary research. Rich metal-based redox processes …
Iron sensitizer converts light to electrons with 92% yield
Solar energy conversion in photovoltaics or photocatalysis involves light harvesting, or
sensitization, of a semiconductor or catalyst as a first step. Rare elements are frequently …
sensitization, of a semiconductor or catalyst as a first step. Rare elements are frequently …
Photoactive iron complexes: more sustainable, but still a challenge
On transition metals such as iron rests lots of hope to replace precious metal catalysts in the
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
Pyrene-Decoration of a Chromium(0) Tris(diisocyanide) Enhances Excited State Delocalization: A Strategy to Improve the Photoluminescence of 3d6 Metal …
C Wegeberg, D Häussinger… - Journal of the American …, 2021 - ACS Publications
There is a long-standing interest in iron (II) complexes that emit from metal-to-ligand charge
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
V Charra, P de Fremont, P Braunstein - Coordination Chemistry Reviews, 2017 - Elsevier
N-Heterocyclic carbene (NHC) ligands are attracting worldwide interest because of their
considerable scope and potential in coordination/organometallic chemistry, catalysis and …
considerable scope and potential in coordination/organometallic chemistry, catalysis and …
Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States
Fe (III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …
Beyond the First Coordination Sphere─ Manipulating the Excited-State Landscape in Iron (II) Chromophores with Protons
K Witas, SS Nair, T Maisuradze, L Zedler… - Journal of the …, 2024 - ACS Publications
Molecular transition metal chromophores play a central role in light harvesting and energy
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
Long-lived, strongly emissive, and highly reducing excited states in Mo (0) complexes with chelating isocyanides
Newly discovered tris (diisocyanide) molybdenum (0) complexes are Earth-abundant
isoelectronic analogues of the well-known class of [Ru (α-diimine) 3] 2+ compounds with …
isoelectronic analogues of the well-known class of [Ru (α-diimine) 3] 2+ compounds with …