Nanozymes: classification, catalytic mechanisms, activity regulation, and applications

Y Huang, J Ren, X Qu - Chemical reviews, 2019 - ACS Publications
Because of the high catalytic activities and substrate specificity, natural enzymes have been
widely used in industrial, medical, and biological fields, etc. Although promising, they often …

Enzymatic halogenation and dehalogenation reactions: pervasive and mechanistically diverse

V Agarwal, ZD Miles, JM Winter, AS Eustáquio… - Chemical …, 2017 - ACS Publications
Naturally produced halogenated compounds are ubiquitous across all domains of life where
they perform a multitude of biological functions and adopt a diversity of chemical structures …

Vanadium pentoxide nanoparticles mimic vanadium haloperoxidases and thwart biofilm formation

F Natalio, R André, AF Hartog, B Stoll… - Nature …, 2012 - nature.com
Marine biofouling—the colonization of small marine microorganisms on surfaces that are
directly exposed to seawater, such as ships' hulls—is an expensive problem that is currently …

Halogenases: a palette of emerging opportunities for synthetic biology–synthetic chemistry and C–H functionalisation

C Crowe, S Molyneux, SV Sharma, Y Zhang… - Chemical Society …, 2021 - pubs.rsc.org
The enzymatic generation of carbon–halogen bonds is a powerful strategy used by both
nature and synthetic chemists to tune the bioactivity, bioavailability and reactivity of …

The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

DC Crans, JJ Smee, E Gaidamauskas… - Chemical reviews, 2004 - ACS Publications
Vanadium is a trace element, which may be beneficial and possibly essential in humans1
but certainly essential for some living organisms. 2r11 Metal ions and thus vanadium ions …

[PDF][PDF] Haloperoxidase mimicry by CeO2− x nanorods combats biofouling

K Herget, P Hubach, S Pusch, P Deglmann, H Götz… - Adv. Mater, 2017 - academia.edu
DOI: 10.1002/adma. 201603823 homoserine lactones (AHLs), a class of signaling
molecules involved in bacterial quorum sensing.[8–10] V-HPO in D. pulchra is located …

Cerium‐Based Metal–Organic Framework with Intrinsic Haloperoxidase‐Like Activity for Antibiofilm Formation

Z Zhou, S Li, G Wei, W Liu, Y Zhang… - Advanced Functional …, 2022 - Wiley Online Library
Biofilms adhering to surfaces have severe impacts on both public health and industry.
Environmentally friendly strategies for combating biofilms are needed due to the biosafety …

Oxidative halogenation with “green” oxidants: oxygen and hydrogen peroxide

A Podgoršek, M Zupan, J Iskra - … Chemie International Edition, 2009 - Wiley Online Library
It is difficult to imagine organic chemistry without organo‐halogen compounds and the
molecular halogens needed for their preparation. The halogens have very different …

Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates

N Mizuno, K Kamata - Coordination Chemistry Reviews, 2011 - Elsevier
Vanadium compounds have attracted much attention because they have widely been used
for homogeneous, heterogeneous, industrial, and biological oxidation processes with alkyl …

Mechanistic considerations of halogenating enzymes

A Butler, M Sandy - Nature, 2009 - nature.com
In nature, halogenation is a strategy used to increase the biological activity of secondary
metabolites, compounds that are often effective as drugs. However, halides are not …