Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Transition metal catalyzed synthesis of aryl sulfides

CC Eichman, JP Stambuli - Molecules, 2011 - mdpi.com
The presence of aryl sulfides in biologically active compounds has resulted in the
development of new methods to form carbon-sulfur bonds. The synthesis of aryl sulfides via …

Heterogeneously Catalyzed Direct C H Thiolation of Heteroarenes

S Vásquez‐Céspedes, A Ferry… - Angewandte Chemie …, 2015 - Wiley Online Library
The first general methodology for the direct thiolation of electron‐rich heteroarenes was
developed by employing Pd/Al2O3, a recoverable and commercially available …

Palladium catalyzed aryl (alkyl) thiolation of unactivated arenes

P Saravanan, P Anbarasan - Organic letters, 2014 - ACS Publications
A general palladium-catalyzed aryl (alkyl) thiolation of various substituted unactivated
arenes is accomplished for the synthesis of diverse unsymmetrical diaryl (alkyl) sulfides in …

Transition-metal-free synthesis of unsymmetrical diaryl chalcogenides from arenes and diaryl dichalcogenides

CD Prasad, SJ Balkrishna, A Kumar… - The Journal of …, 2013 - ACS Publications
A transition-metal-free synthetic method has been developed for the synthesis of
unsymmetrical diaryl chalcogenides (S, Se, and Te) from diaryl dichalcogenides and arenes …

A generic platform for upcycling polystyrene to aryl ketones and organosulfur compounds

NE Munyaneza, C Posada, Z Xu… - Angewandte …, 2023 - Wiley Online Library
Polystyrene (PS) is one of the least recycled large‐volume commodity plastics due to
bulkiness of foam products and associated contaminants. PS recycling is also severely …

Nonclassical biological activities of quinolone derivatives

M Daneshtalab, A Ahmed - Journal of Pharmacy & …, 2012 - journals.library.ualberta.ca
Quinolones are considered as a big family of multi-faceted drugs; their chemical synthesis is
flexible and can be easily adapted to prepare new congeners with rationally devised …

Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution

D Li, S Li, C Peng, L Lu, S Wang, P Wang… - Chemical …, 2019 - pubs.rsc.org
Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–
S bond in a highly straightforward and efficient manner. Various enamines and (hetero) aryl …

Palladium-Catalyzed C–S Coupling: Access to Thioethers, Benzo[b]thiophenes, and Thieno[3,2-b]thiophenes

M Kuhn, FC Falk, J Paradies - Organic Letters, 2011 - ACS Publications
The first C–S bond formation/cross-coupling/cyclization domino reaction using thiourea as a
cheap and easy to handle dihydrosulfide surrogate has been developed. Structurally …

Recyclable iodine-catalyzed oxidative C–H chalcogenation of 1, 1-diarylethenes in water: green synthesis of trisubstituted vinyl sulfides and selenides

N Mukherjee, T Chatterjee - Green Chemistry, 2023 - pubs.rsc.org
We disclose a metal-free, iodine-catalyzed oxidative C–H sulfenylation and selenation of
alkenes, particularly 1, 1-diarylethenes with diorganyl dichalcogenides in water for the cost …