Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere

S Wang, Y Zhao, AWH Chan, M Yao, Z Chen… - Chemical …, 2023 - ACS Publications
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Nanozymes: definition, activity, and mechanisms

M Zandieh, J Liu - Advanced materials, 2024 - Wiley Online Library
Abstract “Nanozyme” is used to describe various catalysts from immobilized inorganic metal
complexes, immobilized enzymes to inorganic nanoparticles. Here, the history of …

Nanomaterials-modulated Fenton reactions: Strategies, chemodynamic therapy and future trends

J Qi, G Jiang, Y Wan, J Liu, F Pi - Chemical Engineering Journal, 2023 - Elsevier
The Fenton reaction refers to the decomposition of hydrogen peroxide catalyzed by ferrous
ions (Fe 2+) to generate hydroxyl radicals (· OH). Due to the strong oxidizing capacities of …

EPR evidence for mechanistic diversity of Cu (II)/peroxygen oxidation systems by tracing the origin of DMPO spin adducts

L Wang, Y Fu, Q Li, Z Wang - Environmental Science & …, 2022 - ACS Publications
Electron paramagnetic resonance (EPR) has been extensively used for the identification of
free radicals that are generated from advanced oxidation processes (AOPs) so as to …

Single-atom-based oxygen reduction reaction catalysts for proton exchange membrane fuel cells: progress and perspective

J Yu, C Su, L Shang, T Zhang - ACS nano, 2023 - ACS Publications
Single-atom catalysts (SACs) are regarded as promising non-noble-metal alternatives for
the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells due to their …

Acceleration of Fe3+/Fe2+ cycle in garland-like MIL-101 (Fe)/MoS2 nanosheets to promote peroxymonosulfate activation for sulfamethoxazole degradation

K Zhu, W Qin, Y Gan, Y Huang, Z Jiang, Y Chen… - Chemical Engineering …, 2023 - Elsevier
Iron-based molybdenum disulfide (Fe-MoS 2) has emerged as a Fenton-like catalyst for the
highly efficient degradation of antibiotics, but the structure–activity relationship remains …

Sustainable chemical upcycling of waste polyolefins by heterogeneous catalysis

M Chu, W Tu, S Yang, C Zhang, Q Li, Q Zhang… - SusMat, 2022 - Wiley Online Library
The mass production of disposable polyolefin products has led to serious plastic pollution
and an imbalance between manufacturing and recycling. Given these challenges, the …

MoS2 as a cocatalyst applied in advanced oxidation processes for enhancing degradation of organic pollutants: a review

MH Fan, CH Wang, X Yu, J Ding, AQ **ao, Y Li… - Tungsten, 2024 - Springer
Fenton technology, as a typical advanced oxidation processes (AOPs), can generate
reactive oxygen species (ROS) of strong oxidation capacity to degrade organic pollutants …

Reaction of FeaqII with Peroxymonosulfate and Peroxydisulfate in the Presence of Bicarbonate: Formation of FeaqIV and Carbonate Radical Anions

A Kottapurath Vijay, V Marks, A Mizrahi… - Environmental …, 2023 - ACS Publications
Many advanced oxidation processes (AOPs) use Fenton-like reactions to degrade organic
pollutants by activating peroxymonosulfate (HSO5–, PMS) or peroxydisulfate (S2O82 …