Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …
functional groups. POs are commonly regarded as chemically labile termination products …
Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization
X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …
Nanozymes: definition, activity, and mechanisms
Abstract “Nanozyme” is used to describe various catalysts from immobilized inorganic metal
complexes, immobilized enzymes to inorganic nanoparticles. Here, the history of …
complexes, immobilized enzymes to inorganic nanoparticles. Here, the history of …
Nanomaterials-modulated Fenton reactions: Strategies, chemodynamic therapy and future trends
J Qi, G Jiang, Y Wan, J Liu, F Pi - Chemical Engineering Journal, 2023 - Elsevier
The Fenton reaction refers to the decomposition of hydrogen peroxide catalyzed by ferrous
ions (Fe 2+) to generate hydroxyl radicals (· OH). Due to the strong oxidizing capacities of …
ions (Fe 2+) to generate hydroxyl radicals (· OH). Due to the strong oxidizing capacities of …
EPR evidence for mechanistic diversity of Cu (II)/peroxygen oxidation systems by tracing the origin of DMPO spin adducts
Electron paramagnetic resonance (EPR) has been extensively used for the identification of
free radicals that are generated from advanced oxidation processes (AOPs) so as to …
free radicals that are generated from advanced oxidation processes (AOPs) so as to …
Single-atom-based oxygen reduction reaction catalysts for proton exchange membrane fuel cells: progress and perspective
Single-atom catalysts (SACs) are regarded as promising non-noble-metal alternatives for
the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells due to their …
the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells due to their …
Acceleration of Fe3+/Fe2+ cycle in garland-like MIL-101 (Fe)/MoS2 nanosheets to promote peroxymonosulfate activation for sulfamethoxazole degradation
K Zhu, W Qin, Y Gan, Y Huang, Z Jiang, Y Chen… - Chemical Engineering …, 2023 - Elsevier
Iron-based molybdenum disulfide (Fe-MoS 2) has emerged as a Fenton-like catalyst for the
highly efficient degradation of antibiotics, but the structure–activity relationship remains …
highly efficient degradation of antibiotics, but the structure–activity relationship remains …
Sustainable chemical upcycling of waste polyolefins by heterogeneous catalysis
The mass production of disposable polyolefin products has led to serious plastic pollution
and an imbalance between manufacturing and recycling. Given these challenges, the …
and an imbalance between manufacturing and recycling. Given these challenges, the …
MoS2 as a cocatalyst applied in advanced oxidation processes for enhancing degradation of organic pollutants: a review
MH Fan, CH Wang, X Yu, J Ding, AQ **ao, Y Li… - Tungsten, 2024 - Springer
Fenton technology, as a typical advanced oxidation processes (AOPs), can generate
reactive oxygen species (ROS) of strong oxidation capacity to degrade organic pollutants …
reactive oxygen species (ROS) of strong oxidation capacity to degrade organic pollutants …
Reaction of FeaqII with Peroxymonosulfate and Peroxydisulfate in the Presence of Bicarbonate: Formation of FeaqIV and Carbonate Radical Anions
A Kottapurath Vijay, V Marks, A Mizrahi… - Environmental …, 2023 - ACS Publications
Many advanced oxidation processes (AOPs) use Fenton-like reactions to degrade organic
pollutants by activating peroxymonosulfate (HSO5–, PMS) or peroxydisulfate (S2O82 …
pollutants by activating peroxymonosulfate (HSO5–, PMS) or peroxydisulfate (S2O82 …