Square-planar d8 metal mixed-ligand dithiolene complexes as second order nonlinear optical chromophores: Structure/property relationship

P Deplano, L Pilia, D Espa, ML Mercuri… - Coordination Chemistry …, 2010 - Elsevier
The structure/property relationship of square-planar d8 metal push/pull mixed-ligand
dithiolene complexes is discussed to provide suitable tools to chemists for tailoring …

Metal dithiolene complexes in olefin addition and purification, small molecule adsorption, H2 evolution and CO2 reduction

J Pitchaimani, SF Ni, L Dang - Coordination Chemistry Reviews, 2020 - Elsevier
The transition metal dithiolene complexes bearing unusual electronic and redox non-
innocent ligands hold a wide range of applications in the fields of optical materials …

Insights into the supramolecular and molecular electrocatalytic properties of 1, 2-bis (diphenylphosphine) ethane appended nickel (ii) 1, 2-dithiosquarate for oxygen …

A Kushwaha, D Srivastava, G Kociok-Köhn… - New Journal of …, 2024 - pubs.rsc.org
A new heteroleptic Ni (II) dithiolate [Nidppe (dtsq)](Nidtsq)(dppe= 1, 2-bis-
(diphenylphosphino) ethane, dtsq2−= 3, 4-dioxocyclobut-1-ene-1, 2-dithiolate) has been …

Immobilized cobalt bis (benzenedithiolate) complexes: exceptionally active heterogeneous electrocatalysts for dihydrogen production from mildly acidic aqueous …

SC Eady, MM MacInnes, N Lehnert - Inorganic chemistry, 2017 - ACS Publications
A series of cobalt bis (benzenedithiolate) complexes with varying benzenedithiolate
(general abbreviation: bdt2–) ring substitutions (S2C6X42–) were prepared and adsorbed …

Computational characterization of redox non-innocence in cobalt-bis (diaryldithiolene)-catalyzed proton reduction

JA Panetier, CS Letko, TD Tilley… - Journal of Chemical …, 2016 - ACS Publications
Localized orbital bonding analysis (LOBA) was employed to probe the oxidation state in
cobalt-bis (diaryldithiolene)-catalyzed proton reduction in nonaqueous media. LOBA …

Density functional theoretical investigation of the aromatic nature of BN substituted benzene and four ring polyaromatic hydrocarbons

D Ghosh, G Periyasamy, SK Pati - Physical Chemistry Chemical …, 2011 - pubs.rsc.org
We have studied the topological and local aromaticity of BN-substituted benzene, pyrene,
chrysene, triphenylene and tetracene molecules. The nucleus-independent chemical …

Redox-switchable chromophores based on metal (Ni, Pd, Pt) mixed-ligand dithiolene complexes showing molecular second-order nonlinear-optical activity

D Espa, L Pilia, L Marchio, ML Mercuri… - Inorganic …, 2011 - ACS Publications
The synthesis and full characterization of the redox-active nickel triad mixed-ligand
dithiolene complexes based on Bz2pipdt= 1, 4-dibenzylpiperazine-3, 2-dithione and dmit= 2 …

Diradical character of neutral heteroleptic bis (1, 2-dithiolene) metal complexes: Case study of [Pd (Me2timdt)(mnt)](Me2timdt= 1, 3-dimethyl-2, 4, 5 …

MC Aragoni, C Caltagirone, V Lippolis… - Inorganic …, 2020 - ACS Publications
The reaction of the bis (1, 2-dithiolene) complex [Pd (Me2timdt) 2](1; Me2timdt•–=
monoreduced 1, 3-dimethyl-2, 4, 5-trithioxoimidazolidine) with Br2 yielded the complex [Pd …

Identifying of charge-transfer transitions and reactive centers in M (diimine)(dithiolate) complexes by DFT techniques

CA Mitsopoulou - Coordination Chemistry Reviews, 2010 - Elsevier
This review is focused on theoretical aspects of mixed diimine–dithiolate complexes by
means of DFT and TD-DFT methods. Thus, the geometry, the character of charge-transfer …

Ni (ii) dithiolate anion composites with two-dimensional materials for electrochemical oxygen evolution reactions (OERs)

A Singh, A Singh, G Kociok-Köhn, KC Molloy… - New Journal of …, 2021 - pubs.rsc.org
In this report, the composites of anionic complex [NEt4][Ni (S2C2Ph2) 2] with two-
dimensional materials such as graphene oxide (GO), reduced graphene oxide (rGO) or …