In synthetic carbohydrate chemistry, the modification of glycosyl radicals pathway stands as
a central area of focus. The radical‐based reactions often demonstrate remarkable …

Glycosyl donor activation emerged as an enabling technology for anomeric
functionalization, but aimed primarily at O-glycosylation. In contrast, we herein disclose …

We demonstrate an efficient, scalable, and stereoselective C-glycosylation with
thioglycosides possessing a unique photoactive tetrafluoropyridin-4-yl (TFPy) thio radical …

Radical C-glycosylation presents a flexible and efficient method for synthesizing C-
glycosides. Existing methods always require multistep processes for generating anomeric …

The synthesis of C1-ketonyl glycosyl compounds featuring α-selectivity has seldom been
reported. We herein devise a glycosyl radical-based approach to facilely access …

Organic synthesis has historically relied on solution‐phase, polar transformations to forge
new bonds. However, this paradigm is evolving, propelled by the rapid evolution of radical …

C-Glycosides are essential for the study of biological processes and the development of
carbohydrate-based drugs. Despite the tremendous hurdles, glycochemists have often …

The glycosylation of peptides and proteins can significantly impact their intrinsic properties,
such as conformation, stability, antigenicity, and immunogenicity. Current methods for …

Readily synthesized bench-stable glycosyl dithioimidocarbonates are useful C-glycoside
precursors. Under mild photochemical conditions, these glycosides undergo desulfurative …

Going beyond currently reported two electron transformations that formed the core backdrop
of asymmetric catalytic site‐selective carbohydrate polyol functionalizations, we herein …