Surface organometallic chemistry has developed as an effective strategy for the rational
design and synthesis of well-defined, single-site Pt-based heterogeneous catalysts. Given …

The synthesis of actinide tetrarhenate complexes completes a series of iridate, osmate, and
rhenate polyhydrides, allowing for structural and bonding comparisons to be made …

Metal-catalyzed hydrogen isotope exchange (HIE) has become a valuable method for
incorporating deuterium and tritium into organic molecules, with applications in a wide range …

We report the synthesis of a heterobimetallic U (III)–Ir species which reacts with CS2 to form
the novel ethanetetrathiolate fragment via hydride insertion and C–C coupling …

Transition-metal hydrides (TMHs) find numerous applications across fields, from catalysis to
H2 storage. Yet, determining the structure of TMHs can remain a challenge, as hydrogen is …

Chapter 1. The field of f-block–transition metal hydride chemistry is introduced and
summarized. Key properties of these compounds such as small molecule activation …