Electronic transport properties of single-molecule junctions have been widely measured by
several techniques, including mechanically controllable break junctions, electromigration …

Single-molecule junctions—devices in which a single molecule is electrically connected by
two electrodes—enable the study of a broad range of quantum-transport phenomena even …

Molecular diodes operating in the tunnelling regime are intrinsically limited to a maximum
rectification ratio R of∼ 103. To enhance this rectification ratio to values comparable to …

Molecular junctions, where single molecules are bound to metal or semiconductor
electrodes, represent a unique architecture to investigate molecules in a distinct …

The convergence of supramolecular chemistry and single‐molecule electronics offers a new
perspective on supramolecular electronics, and provides a new avenue toward …

Although molecular rectifiers were proposed over four decades ago,, until recently reported
rectification ratios (RR) were rather moderate,,,,,,,,–(RR~ 101). This ceiling was convincingly …

Unimolecular current rectifiers are fundamental building blocks in organic electronics.
Rectifying behavior has been identified in numerous organic systems due to electron‐hole …

Polyoxometalates have been proposed in the literature as nanoelectronic components,
where they could offer key advantages with their structural versatility and rich …

The aim of molecular electronics is to miniaturize active electronic devices and ultimately
construct single-molecule nanocircuits using molecules with diverse structures featuring …

This Concept article will give a glimpse into chemical design principles for exploiting
quantum interference (QI) effects in molecular‐scale devices. Direct observation of room …