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Atypical compounds of gases, which have been called 'noble'
W Grochala - Chemical Society Reviews, 2007 - pubs.rsc.org
In this critical review I describe fascinating experimental and theoretical advances in 'noble
gas' chemistry during the last twenty years, and have taken a somewhat unexpected course …
gas' chemistry during the last twenty years, and have taken a somewhat unexpected course …
Noble-gas hydrides: new chemistry at low temperatures
L Khriachtchev, M Räsänen… - Accounts of Chemical …, 2009 - ACS Publications
Noble-gas chemistry has been undergoing a renaissance in recent years, due in large part
to noble-gas hydrides, HNgY, where Ng= noble-gas atom and Y= electronegative fragment …
to noble-gas hydrides, HNgY, where Ng= noble-gas atom and Y= electronegative fragment …
Formation of novel rare-gas molecules in low-temperature matrices
▪ Abstract Progress in the study of a new class of chemically bound compounds of noble-gas
atoms is reviewed. The focus is on rare-gas molecules of the form HNgY, where Ng is a …
atoms is reviewed. The focus is on rare-gas molecules of the form HNgY, where Ng is a …
In quest of strong Be–Ng bonds among the neutral Ng–Be complexes
The global minimum geometries of BeCN2 and BeNBO are linear BeN–CN and BeN–BO,
respectively. The Be center of BeCN2 binds He with the highest Be–He dissociation energy …
respectively. The Be center of BeCN2 binds He with the highest Be–He dissociation energy …
Chemical Compounds Formed from Diacetylene and Rare-Gas Atoms: HKrC4H and HXeC4H
New organic rare-gas compounds, HRgC4H (Rg= Kr or Xe), are identified in matrix-isolation
experiments supported by ab initio calculations. These compounds are the largest …
experiments supported by ab initio calculations. These compounds are the largest …
[HTML][HTML] Astrochemically relevant radicals and radical–molecule complexes: A new insight from matrix isolation
VI Feldman - International Journal of Molecular Sciences, 2023 - mdpi.com
The reactive open-shell species play a very important role in the radiation-induced
molecular evolution occurring in the cold areas of space and presumably leading to the …
molecular evolution occurring in the cold areas of space and presumably leading to the …
Confinement induced binding of noble gas atoms
The stability of Ng n@ B 12 N 12 and Ng n@ B 16 N 16 systems is assessed through a
density functional study and ab initio simulation. Although they are found to be …
density functional study and ab initio simulation. Although they are found to be …
Insertion of noble gas atoms into cyanoacetylene: An ab initio and matrix isolation study
A computational and experimental matrix isolation study of insertion of noble gas atoms into
cyanoacetylene (HCCCN) is presented. Twelve novel noble gas insertion compounds are …
cyanoacetylene (HCCCN) is presented. Twelve novel noble gas insertion compounds are …
Matrix-isolation and ab initio study of HNgCCF and HCCNgF molecules (Ng= Ar, Kr, and Xe)
We report three new noble-gas molecules prepared in low-temperature Kr and Xe matrices
from the HCCF precursor by UV photolysis and thermal annealing. The identified molecules …
from the HCCF precursor by UV photolysis and thermal annealing. The identified molecules …
First compounds with argon–carbon and argon–silicon chemical bonds
Argon is an extremely chemically inert element. HArF is presently the only experimentally
known neutral molecule containing a chemically bound argon atom. Ab initio calculations at …
known neutral molecule containing a chemically bound argon atom. Ab initio calculations at …