Ortho-vanillin became very popular in coordination chemistry because of its Schiff bases,
which generate a rich variety of complexes, ranging from oligonuclear species to …

Heterometallic 3d− 4f complexes are of high interest in molecular magnetism: the lanthanide
ions bring large and, in most cases, anisotropic magnetic moments. The combination of 3d …

The binuclear complexes (3d–3d, 3d–3d′, 3d–4f) with compartmental ligands can
efficiently act as tectons in crystal engineering. Various high nuclearity clusters and …

Design and synthesis of cyanido-bridged d–f molecular assemblies, often accessible via self-
assembly of anionic building-block [M (CN) 6] 3− and lanthanide ions in the presence of …

Heteronuclear cationic complexes, LCuLn 3+ and (LCu) 2Ln 3+, were employed as nodes in
designing high‐nuclearity complexes and coordination polymers with a rich variety of …

This paper reviews the most representative examples of heterometallic complexes
containing three different paramagnetic metal ions, focusing on their magnetic properties …

Herein, we report the synthesis, structural investigation, and magnetic and photophysical
properties of a series of 13 [ZnIILnIII] heterodinuclear complexes, which have been obtained …

The monometallic precursors L1Cu and L2Cu (L1H2 standing for 1, 3-bis ((3-
ethoxysalicylidene) amino) propane and L2H2 standing for 1, 2-bis ((3-methoxysalicylidene) …

A new hetero-bimetallic Zn (II)/Ca (II) complex,[Zn 2 (L OMe-pn) 2 (ƞ 1-NCS) 2 Ca](1) has
been synthesized using a potentially hexadentate N 2 O 4 proligand, H 2 L OMe-pn= N, N …

Two novel 3d–4d heterometallic coordination polymers {[Cu3 (bipy) 3 (H2O) 5][Ag6 (mna) 6]·
11.5 H2O} n (1) and {[Zn3 (eda) 3 (H2O) 4][Ag6 (mna) 6]· 8H2O} n (2) were synthesized …