Molecular spin crossover phenomenon: recent achievements and prospects

A Bousseksou, G Molnár, L Salmon… - Chemical Society …, 2011 - pubs.rsc.org
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …

Spin-transition polymers: from molecular materials toward memory devices

O Kahn, CJ Martinez - Science, 1998 - science.org
Some 3dn (4≤ n≤ 7) transition metal compounds exhibit a cooperative transition between a
low-spin (LS) and a high-spin (HS) state. This transition is abrupt and occurs with a thermal …

Cooperative phenomena and light-induced bistability in iron (II) spin-crossover compounds

A Hauser, J Jeftić, H Romstedt, R Hinek… - Coordination chemistry …, 1999 - Elsevier
In iron (II) spin-crossover compounds, the transition from the 1A1 low-spin state at low
temperatures to the 5T2 high-spin state at elevated temperatures is accompanied by a large …

Calorimetric investigation of phase transitions occurring in molecule-based magnets

M Sorai, M Nakano, Y Miyazaki - Chemical reviews, 2006 - ACS Publications
Magnetism is one of the important functionalities of materials and has been a basic research
subject to understand materials. Magnetism has been explored mainly in the field of solid …

Monte Carlo simulation of pressure-induced phase transitions in spin-crossover materials

Y Konishi, H Tokoro, M Nishino, S Miyashita - Physical review letters, 2008 - APS
Pressure-induced phase transitions of spin-crossover materials are studied in a microscopic
model taking into account the elastic interaction among distortions of lattice due to the …

Metal Dilution Effects on the Spin-Crossover Properties of the Three-Dimensional Coordination Polymer Fe(pyrazine)[Pt(CN)4]

T Tayagaki, A Galet, G Molnár, MC Munoz… - The Journal of …, 2005 - ACS Publications
The 1A1⇆ 5T2 spin transition has been investigated in the solid solutions of Fe x M1-x
(pyrazine)[Pt (CN) 4](M= Ni or Co, 0≤ x≤ 1) having a three-dimensional polynuclear …

<? ACS-CT-START-Insert?> Update 1 of:<? ACS-CT-END-Insert?> Calorimetric Investigation of Phase Transitions Occurring in Molecule-Based Magnets

M Sorai… - Chemical …, 2013 - ACS Publications
1.1. Scope Magnetism is one of the important functionalities of materials and has been a
basic research subject to understand materials. Magnetism has been explored mainly in the …

Three-dimensional electroelastic modeling of the nucleation and propagation of the spin domains in spin-crossover materials

N Di Scala, NEI Belmouri, MAP Espejo… - Physical Review B, 2022 - APS
A three-dimensional version of the electroelastic model allowing the description of spin-
crossover (SCO) materials taking into account for the volume change at the transition …

Two-variable anharmonic model for spin-crossover solids: A like-spin domains interpretation

W Nicolazzi, S Pillet, C Lecomte - Physical Review B—Condensed Matter and …, 2008 - APS
Spin-crossover (SC) complexes are one of the most fascinating examples of molecular
bistability, whose solid-state properties are tightly connected to cooperative interactions …

Primary role of the electrostatic contributions in a rational growth of hysteresis loop in spin-crossover Fe (II) complexes

M Kepenekian, B Le Guennic… - Journal of the American …, 2009 - ACS Publications
We report a comprehensive analysis of the hysteresis behavior in a series of well-
characterized spin-crossover Fe (II) materials. On the basis of the available X-ray data and …