Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Radical polymerization of acrylic monomers: An overview
N Ballard, JM Asua - Progress in Polymer Science, 2018 - Elsevier
Since their discovery and development in the 20th century, acrylic polymers have become
an integral part of numerous industries and are used in a myriad of applications. As is true …
an integral part of numerous industries and are used in a myriad of applications. As is true …
Gillespie-driven kinetic Monte Carlo algorithms to model events for bulk or solution (bio) chemical systems containing elemental and distributed species
Stochastic modeling techniques have emerged as a powerful tool to study the time evolution
of processes in many research fields including (bio) chemical engineering and biology. One …
of processes in many research fields including (bio) chemical engineering and biology. One …
Translating simulated chain length and molar mass distributions in chain‐growth polymerization for experimental comparison and mechanistic insight
The molar mass distribution (MMD), which is also known as the molecular weight distribution
(MWD), is a key molecular property for a polymerization process, as it determines polymer …
(MWD), is a key molecular property for a polymerization process, as it determines polymer …
Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well …
M Edeleva, YW Marien, PHM Van Steenberge… - Polymer …, 2021 - pubs.rsc.org
The radical chemistry of polyacrylate synthesis is non-trivial, due to a significant amount of
side reactions. Backbiting transforms conventional secondary end-chain radicals (ECRs) in …
side reactions. Backbiting transforms conventional secondary end-chain radicals (ECRs) in …
Connecting gas-phase computational chemistry to condensed phase kinetic modeling: The state-of-the-art
M Edeleva, PHM Van Steenberge, MK Sabbe… - Polymers, 2021 - mdpi.com
In recent decades, quantum chemical calculations (QCC) have increased in accuracy, not
only providing the ranking of chemical reactivities and energy barriers (eg, for optimal …
only providing the ranking of chemical reactivities and energy barriers (eg, for optimal …
Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates
M Edeleva, YW Marien… - Reaction Chemistry & …, 2021 - pubs.rsc.org
Conventional batch solution free radical polymerization (FRP) of n-butyl acrylate (nBuA) with
thermal initiators such as 2, 2′-azobis (2-methylpropionitrile)(AIBN) is known to be strongly …
thermal initiators such as 2, 2′-azobis (2-methylpropionitrile)(AIBN) is known to be strongly …
From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization
Arrhenius parameters for backbiting (bb), mid-chain radical propagation (pm) and β-scission
in n-butyl acrylate radical polymerization are determined based on pulsed laser …
in n-butyl acrylate radical polymerization are determined based on pulsed laser …
Molecularly imprinted polymers with enhanced selectivity based on 4-(aminomethyl) pyridine-functionalized poly (2-oxazoline) s for detecting hazardous herbicide …
The detection of hazardous compounds is of importance to control (drinking) water quality.
Here, we report the development of poly (2-oxazoline)-based molecularly imprinted …
Here, we report the development of poly (2-oxazoline)-based molecularly imprinted …
Kinetic Monte Carlo modeling extracts information on chain initiation and termination from complete PLP-SEC traces
YW Marien, PHM Van Steenberge… - …, 2017 - ACS Publications
Complete pulsed laser polymerization (PLP) log-molar mass distributions (log-MMDs) are
accurately simulated using kinetic Monte Carlo (k MC) modeling to gain not only knowledge …
accurately simulated using kinetic Monte Carlo (k MC) modeling to gain not only knowledge …