Ag-based catalysts in heterogeneous selective oxidation of alcohols: a review

VV Torbina, AA Vodyankin, S Ten, GV Mamontov… - Catalysts, 2018‏ - mdpi.com
Alcohols (bioalcohols) is a class of chemicals that are used as a feedstock for the
manufacturing of a large number of valuable intermediates in industrially important …

Formaldehyde production using methanol and heterogeneous solid catalysts: A comprehensive review

HI Mahdi, NN Ramlee, DH da Silva Santos… - Molecular …, 2023‏ - Elsevier
Despite formaldehyde's high toxicity, it has widespread demand worldwide due to its
applications in the synthesis of a plethora of important chemicals like urea-formaldehyde …

Industrial production of formaldehyde using polycrystalline silver catalyst

GJ Millar, M Collins - Industrial & Engineering Chemistry Research, 2017‏ - ACS Publications
We report the first comprehensive review of the industrial process for the catalytic partial
oxidation of methanol to formaldehyde using silver catalyst. Formaldehyde remains a key …

A mechanistic study on soot oxidation over CeO2–Ag catalyst with 'rice-ball'morphology

K Yamazaki, T Kayama, F Dong, H Shinjoh - Journal of catalysis, 2011‏ - Elsevier
A CeO2–Ag catalyst with a 'rice-ball'morphology, consisting of Ag particles in the center
surrounded by fine CeO2 particles, exhibits exceptional catalytic performance for soot …

Thermodynamic and spectroscopic properties of oxygen on silver under an oxygen atmosphere

TE Jones, TCR Rocha, A Knop-Gericke… - Physical Chemistry …, 2015‏ - pubs.rsc.org
We report on a combined density functional theory and the experimental study of the O1s
binding energies and X-ray Absorption Near Edge Structure (XANES) of a variety of oxygen …

Atomic, molecular and hybrid oxygen structures on silver

Z Tang, T Chen, K Liu, H Du, SG Podkolzin - Langmuir, 2021‏ - ACS Publications
Interactions between oxygen and silver are important in many areas of science and
technology, including materials science, medical, biomedical and environmental …

Surface chemistry of group IB metals and related oxides

W Huang, G Sun, T Cao - Chemical Society Reviews, 2017‏ - pubs.rsc.org
Understanding the surface chemistry of solid catalysts is of great importance for the rational
design of structures of advanced catalysts; however, long-term challenges remain due to the …

Reversible restructuring of silver particles during ethylene epoxidation

AJF van Hoof, IAW Filot, H Friedrich, EJM Hensen - ACS catalysis, 2018‏ - ACS Publications
The restructuring of a silver catalyst during ethylene epoxidation under industrially relevant
conditions was investigated without and with vinyl chloride (VC) promotion. During non-VC …

Formaldehyde selectivity in methanol partial oxidation on silver: Effect of reactive oxygen species, surface reconstruction, and stability of intermediates

M Karatok, MG Sensoy, EI Vovk, H Ustunel… - ACS …, 2021‏ - ACS Publications
Selective oxidation reactions on heterogeneous silver catalysts are essential for the mass
production of numerous industrial commodity chemicals. However, the nature of active …

One-step butadiene synthesis via gas-phase prins condensation of propylene with formaldehyde over heteropolyacid catalysts

PA Kots, MA Artsiusheuski, YV Grigoriev… - ACS Catalysis, 2020‏ - ACS Publications
Gas-phase continuous synthesis of butadiene from propene and formaldehyde has been
studied over heteropolyacids (HPA) supported on silica. Silicotungstic acid (SiW) is found to …