Designing electrolytes and interphases for high-energy lithium batteries

H Wan, J Xu, C Wang - Nature Reviews Chemistry, 2024 - nature.com
High-energy and stable lithium-ion batteries are desired for next-generation electric devices
and vehicles. To achieve their development, the formation of stable interfaces on high …

Emerging electrolytes with fluorinated solvents for rechargeable lithium-based batteries

Y Wang, Z Li, Y Hou, Z Hao, Q Zhang, Y Ni… - Chemical Society …, 2023 - pubs.rsc.org
Electrolytes that can ensure the movement of ions and regulate interfacial chemistries for
fast mass and charge transfer are essential in many types of electrochemical energy storage …

Homogeneous and mechanically stable solid–electrolyte interphase enabled by trioxane-modulated electrolytes for lithium metal batteries

QK Zhang, XQ Zhang, J Wan, N Yao, TL Song, J **e… - Nature Energy, 2023 - nature.com
The solid–electrolyte interphase (SEI) in lithium (Li) metal batteries is often heterogeneous,
containing a diverse range of species and has poor mechanical stability. The SEI undergoes …

Fluorine chemistry in rechargeable batteries: Challenges, progress, and perspectives

Y Wang, X Yang, Y Meng, Z Wen, R Han, X Hu… - Chemical …, 2024 - ACS Publications
The renewable energy industry demands rechargeable batteries that can be manufactured
at low cost using abundant resources while offering high energy density, good safety, wide …

Single-phase local-high-concentration solid polymer electrolytes for lithium-metal batteries

W Zhang, V Koverga, S Liu, J Zhou, J Wang, P Bai… - Nature Energy, 2024 - nature.com
Solid polymers are promising electrolytes for Li-metal batteries, but they have limitations:
they cannot simultaneously achieve high ionic conductivity, good mechanical strength and …

Insights into the solvation chemistry in liquid electrolytes for lithium-based rechargeable batteries

P **ao, X Yun, Y Chen, X Guo, P Gao, G Zhou… - Chemical Society …, 2023 - pubs.rsc.org
Lithium-based rechargeable batteries have dominated the energy storage field and attracted
considerable research interest due to their excellent electrochemical performance. As …

Designing an asymmetric ether-like lithium salt to enable fast-cycling high-energy lithium metal batteries

Y **a, P Zhou, X Kong, J Tian, W Zhang, S Yan, W Hou… - Nature Energy, 2023 - nature.com
Conventional carbonate-based electrolytes with high corrosion towards Li metal result in
massive dendrite growth and limited cycling life, particularly true for practical Li-metal …

Methylation enables the use of fluorine-free ether electrolytes in high-voltage lithium metal batteries

AM Li, O Borodin, TP Pollard, W Zhang, N Zhang… - Nature Chemistry, 2024 - nature.com
Lithium metal batteries represent a promising technology for next-generation energy
storage, but they still suffer from poor cycle life due to lithium dendrite formation and cathode …

A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries

G Zhang, J Chang, L Wang, J Li, C Wang… - Nature …, 2023 - nature.com
The electrochemical stability window of the electrolyte solution limits the energy content of
non-aqueous lithium metal batteries. In particular, although electrolytes comprising …

High‐energy lithium‐ion batteries: recent progress and a promising future in applications

J Xu, X Cai, S Cai, Y Shao, C Hu, S Lu… - Energy & …, 2023 - Wiley Online Library
It is of great significance to develop clean and new energy sources with high‐efficient
energy storage technologies, due to the excessive use of fossil energy that has caused …