Density functional theory is straying from the path toward the exact functional

MG Medvedev, IS Bushmarinov, J Sun, JP Perdew… - Science, 2017 - science.org
The theorems at the core of density functional theory (DFT) state that the energy of a many-
electron system in its ground state is fully defined by its electron density distribution. This …

[PDF][PDF] A brief review on importance of DFT in drug design

H Tandon, T Chakraborty, V Suhag - Res. Med. Eng. Sci, 2019 - researchgate.net
Abstract Density Functional Theory (DFT) is progressively becoming vital for the drug
designing process. Since past few years DFT has appeared as a Quantum Mechanical (QM) …

Performance of B3LYP density functional methods for a large set of organic molecules

J Tirado-Rives, WL Jorgensen - Journal of chemical theory and …, 2008 - ACS Publications
Testing of the commonly used hybrid density functional B3LYP with the 6-31G (d), 6-31G (d,
p), and 6-31+ G (d, p) basis sets has been carried out for 622 neutral, closed-shell organic …

Development of new density functional approximations

NQ Su, X Xu - Annual Review of Physical Chemistry, 2017 - annualreviews.org
Kohn–Sham density functional theory has become the leading electronic structure method
for atoms, molecules, and extended systems. It is in principle exact, but any practical …

Rungs 1 to 4 of DFT Jacob's ladder: Extensive test on the lattice constant, bulk modulus, and cohesive energy of solids

F Tran, J Stelzl, P Blaha - The Journal of chemical physics, 2016 - pubs.aip.org
A large panel of old and recently proposed exchange-correlation functionals belonging to
rungs 1 to 4 of Jacob's ladder of density functional theory are tested (with and without a …

W4-11: A high-confidence benchmark dataset for computational thermochemistry derived from first-principles W4 data

A Karton, S Daon, JML Martin - Chemical Physics Letters, 2011 - Elsevier
We show that the purely first-principles Weizmann-4 (W4) computational thermochemistry
method developed in our group can reproduce available Active Thermochemical Tables …

Benchmarking the performance of time-dependent density functional methods

SS Leang, F Zahariev, MS Gordon - The Journal of chemical physics, 2012 - pubs.aip.org
The performance of 24 density functionals, including 14 meta-generalized gradient
approximation (mGGA) functionals, is assessed for the calculation of vertical excitation …

A well-tempered density functional theory of electrons in molecules

E Livshits, R Baer - Physical Chemistry Chemical Physics, 2007 - pubs.rsc.org
This Invited Article reports extensions of a recently developed approach to density functional
theory with correct long-range behavior (R. Baer and D. Neuhauser, Phys. Rev. Lett., 2005 …

Performance on molecules, surfaces, and solids of the Wu-Cohen GGA exchange-correlation energy functional

F Tran, R Laskowski, P Blaha, K Schwarz - Physical Review B—Condensed …, 2007 - APS
We present the results of Kohn-Sham calculations on molecules, surfaces, and solids which
were obtained using a recently proposed exchange-correlation energy functional [Z. Wu and …

Evaluation of density functional theory for a large and diverse set of organic and inorganic equilibrium structures

A Karton, PR Spackman - Journal of Computational Chemistry, 2021 - Wiley Online Library
Density functional theory (DFT) has been extensively benchmarked for energetic properties;
however, less attention has been given to equilibrium structures and the effect of using a …