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Organoboron-mediated polymerizations
The scientific community has witnessed extensive developments and applications of
organoboron compounds as synthetic elements and metal-free catalysts for the construction …
organoboron compounds as synthetic elements and metal-free catalysts for the construction …
Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …
any metal contaminants in most applications have directed research towards significant …
Silylium ions: from elusive reactive intermediates to potent catalysts
HFT Klare, L Albers, L Süsse, S Keess… - Chemical …, 2021 - ACS Publications
The history of silyl cations has all the makings of a drama but with a happy ending. Being
considered reactive intermediates impossible to isolate in the condensed phase for …
considered reactive intermediates impossible to isolate in the condensed phase for …
Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen do**
Owing to the difficulty in controlling the dopant or defect types and their homogeneity in
carbon materials, it is still a controversial issue to identify the active sites of carbon-based …
carbon materials, it is still a controversial issue to identify the active sites of carbon-based …
Perspective on Lewis Acid‐Base Interactions in Emerging Batteries
Lewis acid‐base interactions are common in chemical processes presented in diverse
applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The …
applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The …
Modular organoboron catalysts enable transformations with unprecedented reactivity
Conspectus Electron-deficient boron-based catalysts with metal-free but metallomimetic
characteristics provide a versatile platform for chemical transformations. However, their …
characteristics provide a versatile platform for chemical transformations. However, their …
Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones
The development of sustainable polymers that possess useful material properties
competitive with existing petroleum-derived polymers is a crucial goal but remains a …
competitive with existing petroleum-derived polymers is a crucial goal but remains a …
New directions for frustrated Lewis pair chemistry
The concerted action of a Lewis acid and base can activate H 2 and other small molecules.
Such frustrated Lewis pairs (FLPs) have garnered much attention and prompted many …
Such frustrated Lewis pairs (FLPs) have garnered much attention and prompted many …
[HTML][HTML] Recent advances in degradable synthetic polymers for biomedical applications‐Beyond polyesters
Polyesters have been studied intensely over the last few decades and proved to be suitable
for a wide range of applications. Despite all benefits, drawbacks such as eg the acidification …
for a wide range of applications. Despite all benefits, drawbacks such as eg the acidification …
Main group metal polymerisation catalysts
With sustainability at the forefront of current polymerisation research, the typically earth-
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …