Construction and application of base-stable MOFs: a critical review

K Wang, Y Li, LH **e, X Li, JR Li - Chemical Society Reviews, 2022 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …

Metal–organic frameworks and their derivatives as electrocatalysts for the oxygen evolution reaction

J Du, F Li, L Sun - Chemical Society Reviews, 2021 - pubs.rsc.org
Electrochemical water splitting is an appealing and promising approach for energy
conversion and storage. As a key half-reaction of electricity-driven water splitting, the oxygen …

Engineering single-atom sites into pore-confined nanospaces of porphyrinic metal–organic frameworks for the highly efficient photocatalytic hydrogen evolution …

Q Mo, L Zhang, S Li, H Song, Y Fan… - Journal of the American …, 2022 - ACS Publications
As a type of heterogeneous catalyst expected for the maximum atom efficiency, a series of
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …

Metal–organic framework derived nanozymes in biomedicine

D Wang, D Jana, Y Zhao - Accounts of chemical research, 2020 - ACS Publications
Conspectus Nanozymes, which integrate the advantages of both nanomaterials and natural
enzymes, have accumulated enormous research interest over the past decades because of …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

Biocatalytic cascades driven by enzymes encapsulated in metal–organic framework nanoparticles

WH Chen, M Vázquez-González, A Zoabi… - Nature Catalysis, 2018 - nature.com
Biocatalytic transformations in cells, such as enzyme cascades, involve complex networks
proceeding in spatially confined microenvironments. Here, inspired by nature, we …

Large cages of zeolitic imidazolate frameworks

H Wang, X Pei, MJ Kalmutzki, J Yang… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The design and synthesis of permanently porous materials with extended cage
structures is a long-standing challenge in chemistry. In this Account, we highlight the unique …

Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs

F Ambroz, TJ Macdonald, V Martis, IP Parkin - Small methods, 2018 - Wiley Online Library
Surface area determination with the Brunauer–Emmett–Teller (BET) method is a widely
used characterization technique for metal–organic frameworks (MOFs). Since these …

Defective metal‐organic frameworks

S Dissegna, K Epp, WR Heinz, G Kieslich… - Advanced …, 2018 - Wiley Online Library
The targeted incorporation of defects into crystalline matter allows for the manipulation of
many properties and has led to relevant discoveries for optimized and even novel …