Removing Neighboring Ring Influence in Monocyclic B–OH Diazaborines: Properties and Reactivity as Phenolic Bioisosteres with Dynamic Hydroxy Exchange
The design of small molecules with unique geometric profiles or molecular connectivity
represents an intriguing yet neglected challenge in modern organic synthesis. This …
represents an intriguing yet neglected challenge in modern organic synthesis. This …
The Effect of Carborane Substituents on the Lewis Acidity of Boranes
The Lewis acidity of primary, secondary, and tertiary boranes with phenyl,
pentafluorophenyl, and all three isomers of the C-substituted icosahedral carboranes (ortho …
pentafluorophenyl, and all three isomers of the C-substituted icosahedral carboranes (ortho …
Bis(1‐Methyl‐ortho‐Carboranyl)Borane
Abstract The Lewis superacid, bis (1‐methyl‐ortho‐carboranyl) borane, is rapidly accessed
in two steps. It is a very effective hydroboration reagent capable of B− H addition to alkenes …
in two steps. It is a very effective hydroboration reagent capable of B− H addition to alkenes …
Carborane–arene fused boracyclic analogues of polycyclic aromatic hydrocarbons accessed by intramolecular borylation
Arenes are 2D aromatics while dicarbadodecaborane clusters are branded as 3D aromatic
molecules. In this work we prepare molecules that feature fused 2D/3D aromatic systems …
molecules. In this work we prepare molecules that feature fused 2D/3D aromatic systems …
Synthesis of phenanthrylboroles and formal nitrene insertion to access azaborapyrenes
Extended conjugation has been introduced into boroles but only on the 2, 3-or 4, 5-positions
of the central BC4 core. In this work we synthesize phenanthrylboroles that also have …
of the central BC4 core. In this work we synthesize phenanthrylboroles that also have …
Unlocking Heteroaromatic Ring Systems through Chalcogen Insertion into Boroles
T Bischof, N Wieprecht, S Fuchs, L Endres… - Inorganic …, 2023 - ACS Publications
In this work, we report the reactivity of various annulated borole derivatives toward
chalcogen (O, S, and Se) insertion. Among a series of 9-borafluorenes with different boron …
chalcogen (O, S, and Se) insertion. Among a series of 9-borafluorenes with different boron …
One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives
JL Bohlen, N Wieprecht, M Arrowsmith… - Chemical …, 2024 - pubs.rsc.org
One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives -
Chemical Communications (RSC Publishing) DOI:10.1039/D4CC04433A Royal Society of …
Chemical Communications (RSC Publishing) DOI:10.1039/D4CC04433A Royal Society of …
Probing borafluorene B–C bond insertion with gold acetylide and azide
Probing borafluorene B–C bond insertion with gold acetylide and azide - Dalton Transactions
(RSC Publishing) DOI:10.1039/D2DT03672J Royal Society of Chemistry View PDF …
(RSC Publishing) DOI:10.1039/D2DT03672J Royal Society of Chemistry View PDF …
Synthesis and characterization of azulene-based BO-doped heteroaromatics
Simultaneously incorporating heteroatoms and nonbenzenoid aromatic hydrocarbons, such
as azulene, into polycyclic aromatic hydrocarbons, offers a robust strategy for designing …
as azulene, into polycyclic aromatic hydrocarbons, offers a robust strategy for designing …
The Effect of Carborane Substituents on the Lewis Acidity of Boranes
The Lewis acidity of primary, secondary, and tertiary boranes with phenyl,
pentafluorophenyl, and all three isomers of icosahedral carboranes (ortho, meta, and para) …
pentafluorophenyl, and all three isomers of icosahedral carboranes (ortho, meta, and para) …