Nonplanar porphyrins: synthesis, properties, and unique functionalities
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …
and chemical applications derived from metal chelation in the core and the 18π aromatic …
Porphyrin Atropisomerism as a Molecular Engineering Tool in Medicinal Chemistry, Molecular Recognition, Supramolecular Assembly, and Catalysis
Porphyrin atropisomerism, which arises from restricted σ‐bond rotation between the
macrocycle and a sufficiently bulky substituent, was identified in 1969 by Gottwald and …
macrocycle and a sufficiently bulky substituent, was identified in 1969 by Gottwald and …
Unraveling the pivotal role of atropisomerism for cellular internalization
C Donohoe, FA Schaberle… - Journal of the …, 2022 - ACS Publications
The intrinsic challenge of large molecules to cross the cell membrane and reach intracellular
targets is a major obstacle for the development of new medicines. We report how rotation …
targets is a major obstacle for the development of new medicines. We report how rotation …
Importance of molecular symmetry for enantiomeric excess recognition by NMR
Recently prochiral solvating agents (pro-CSA) came under the spotlight for the detection of
enantiopurity by NMR. Chemical shift non-equivalency in achiral hosts introduced by the …
enantiopurity by NMR. Chemical shift non-equivalency in achiral hosts introduced by the …
[PDF][PDF] Supramolecular structure of five-coordinate [(4-methyl-2, 6-dinitrophenolato)(octaethylporphinato) iron (III)] heme complex
SA Kohnhorst - Journal of Current Science and Technology, 2023 - researchgate.net
The crystallographic and spectroscopic characterization of the phenolate complex of [(4-
methyl-2, 6-dinitrophenolato)(2, 3, 7, 8, 12, 13, 17, 18-octaethylporphinato) Fe (III)],[FeIII …
methyl-2, 6-dinitrophenolato)(2, 3, 7, 8, 12, 13, 17, 18-octaethylporphinato) Fe (III)],[FeIII …
From Form to Function–Fabricating Functional Porphyrins
MO Sengea - mapyro.chimie.unistra.fr
Porphyrins are nature's cofactors par excellence. Next to oxygen transport and storage, their
role in electron transport and as photosynthetic pigments, they catalyze a multitude of …
role in electron transport and as photosynthetic pigments, they catalyze a multitude of …