The development of homogeneous iron catalysts has been a prolific research field in recent
years. Many catalytic reactions are no longer limited to noble metals. The use of N …

Rigid terdentate 'pincer'ligands containing a bridgehead N-heterocyclic carbene (NHC)
donor attract considerable interest as spectators in transition metal complexes with broad …

Both imidazol-2-ylidene (ImNHC) and 1, 2, 3-triazol-5-ylidene (tzNHC) have evolved to be
elite groups of N-heterocyclic carbene (NHC) ligands for homogeneous catalysis. To …

The current benchmark study is focused on determining the most precise theoretical method
for optimizing the geometry of transition metal–dinitrogen complexes. To accomplish this …

A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen
complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This …

Through the strategy of combining bifunctional 2-hydroxypyridine and a thermally stable N-
heterocyclic carbene ligand, an Ir-catalyzed N-monoalkylation reaction has been developed …

The binding and activation of boranes by transition-metal compounds are relevant to
catalytic hydroboration reactions. Herein, we report the stoichiometric reactivity of a piano …

We report the syntheses and catalytic activity of a series of piano-stool iron complexes with
the general formula [FeClCp*(NHC)](where NHC= N-heterocyclic carbene) toward the gem …

The complex [FeClCp*(HL)](1; where HL= 3-methyl-1-(2-picolyl)-imidazol-2-ylidene) was
synthesized from the reaction of the in situ generated HL ligand and [FeClCp*(TMEDA)] …

A series of piano-stool Fe–NHC complexes have been prepared and characterized. The
NHC ligands used herein possess a benzyl and a mesityl wingtip groups and have different …