Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Chemistry of iron sulfides

D Rickard, GW Luther - Chemical reviews, 2007 - ACS Publications
The iron sulfides constitute a diverse group of solids and dissolved complexes many of
which play key roles in marine systems. The group is particularly complex in the lower …

Redox classification and calibration of redox thresholds in sedimentary systems

TJ Algeo, C Li - Geochimica et Cosmochimica Acta, 2020 - Elsevier
Existing redox classifications and the calibrations of elemental proxies to modern
environmental redox scales are in need of re-evaluation. Here, we review environmental …

The size distribution of framboidal pyrite in modern sediments: an indicator of redox conditions

RT Wilkin, HL Barnes, SL Brantley - Geochimica et cosmochimica acta, 1996 - Elsevier
Pyrite framboids are densely packed, generally spherical aggregates of submicron-sized
pyrite crystals. In this study, a survey was made of framboid size distributions in recently …

Bacterial and thermochemical sulfate reduction in diagenetic settings—old and new insights

HG Machel - Sedimentary geology, 2001 - Elsevier
The association of dissolved sulfate and hydrocarbons is thermodynamically unstable in
virtually all diagenetic environments. Hence, redox-reactions occur, whereby sulfate is …

Pyritization of trace metals in anoxic marine sediments

MA Huerta-Diaz, JW Morse - Geochimica et Cosmochimica Acta, 1992 - Elsevier
The pyritization of reactive trace elements in different anoxic marine sediments was
investigated to determine the importance of factors such as∑ H 2 S, reactive-Fe, pyrite …

The relevance of phosphorus and iron chemistry to the recovery of phosphorus from wastewater: a review

P Wilfert, PS Kumar, L Korving… - … science & technology, 2015 - ACS Publications
The addition of iron is a convenient way for removing phosphorus from wastewater, but this
is often considered to limit phosphorus recovery. Struvite precipitation is currently used to …

Sulfidation of iron-based materials: a review of processes and implications for water treatment and remediation

D Fan, Y Lan, PG Tratnyek, RL Johnson… - … science & technology, 2017 - ACS Publications
Iron-based materials used in water treatment and groundwater remediation especially
micro-and nanosized zerovalent iron (nZVI) can be more effective when modified with …

Chemical influences on trace metal-sulfide interactions in anoxic sediments

JW Morse, GW Luther Iii - Geochimica et Cosmochimica Acta, 1999 - Elsevier
Interactions of trace metals with sulfide in anoxic environments are important in determining
their chemical form and potential toxicity to organisms. In recent years, a considerable body …

Formation processes of framboidal pyrite

RT Wilkin, HL Barnes - Geochimica et Cosmochimica Acta, 1997 - Elsevier
Pyrite framboid formation may be the result of four consecutive processes:(1) nucleation and
growth of initial iron monosulfide microcrystals;(2) reaction of the microcrystals to greigite …