Determination of sets of solute descriptors from chromatographic measurements

MH Abraham, A Ibrahim, AM Zissimos - Journal of Chromatography A, 2004 - Elsevier
The use of gas–liquid chromatographic (GLC) retention data to obtain sets of solute
descriptors is outlined, with reference to the schemes of Laffort and of Weckwerth. The …

Solubility interactions and the design of chemically selective sorbent coatings for chemical sensors and arrays

JW Grate, MH Abraham - Sensors and Actuators B: Chemical, 1991 - Elsevier
A continual challenge in the field of chemical detection is the development of approaches to
designing microsensors and microsensor-based detectors with high selectivity. No single …

[BUCH][B] Handbook of physical-chemical properties and environmental fate for organic chemicals

D Mackay, WY Shiu, SC Lee - 2006 - taylorfrancis.com
CHOICE Award WinnerTransport and transformation processes are key for determining how
humans and other organisms are exposed to chemicals. These processes are largely …

Applications of polyparameter linear free energy relationships in environmental chemistry

S Endo, KU Goss - Environmental science & technology, 2014 - ACS Publications
Partitioning behavior of organic chemicals has tremendous influences on their
environmental distribution, reaction rates, bioaccumulation, and toxic effects. Polyparameter …

[BUCH][B] The essence of chromatography

CF Poole - 2003 - books.google.com
The knowledge base of chromatography continued to expand throughout the 1990s owing
to its many applications to problems of contemporary interest in industry, life and …

Hydrogen bonding. 32. An analysis of water‐octanol and water‐alkane partitioning and the Δlog p parameter of seiler

MH Abraham, HS Chadha, GS Whiting… - Journal of …, 1994 - Wiley Online Library
A general linear solvation energy equation has been used to analyze published partition
coefficients in the systems water‐octanol (613 solutes), water‐hexadecane (370 solutes) …

Hydrogen bonding. Part 34. The factors that influence the solubility of gases and vapours in water at 298 K, and a new method for its determination

MH Abraham, J Andonian-Haftvan… - Journal of the …, 1994 - pubs.rsc.org
The solubility of 408 gaseous compounds in water at 298 K has been correlated through
eqn.(i), where the solubility is expressed as the Ostwald solubility coefficient, Lw, and the …

Classification of stationary phases and other materials by gas chromatography

MH Abraham, CF Poole, SK Poole - Journal of Chromatography A, 1999 - Elsevier
The origin and evolution of solute descriptors for use in the solvation parameter model
applied to the classification of stationary phases and other materials by gas chromatography …

Linear free energy relationships used to evaluate equilibrium partitioning of organic compounds

KU Goss, RP Schwarzenbach - Environmental science & …, 2001 - ACS Publications
In environmental chemistry, one often wants to interpret or predict equilibrium partitioning of
organic compounds between any two phases. Hence, one needs to understand the partition …

Experimental determination of air/water partition coefficients for 21 per-and polyfluoroalkyl substances reveals variable performance of property prediction models

S Endo, J Hammer, S Matsuzawa - Environmental Science & …, 2023 - ACS Publications
Per-and polyfluoroalkyl substances (PFAS) are a group of chemicals of high environmental
concern. However, reliable data for the air/water partition coefficients (K aw), which are …