Recent developments in the methods and applications of the bond valence model

ID Brown - Chemical reviews, 2009 - ACS Publications
The bond valence model was described comprehensively in my 2002 book, The Chemical
Bond in Inorganic Chemistry: The Bond Valence Model, 1 where references to earlier work …

A review of the structural architecture of tellurium oxycompounds

AG Christy, SJ Mills, AR Kampf - Mineralogical Magazine, 2016 - cambridge.org
Relative to its extremely low abundance in the Earth's crust, tellurium is the most
mineralogically diverse chemical element, with over 160 mineral species known that contain …

SoftBV–a software tool for screening the materials genome of inorganic fast ion conductors

H Chen, LL Wong, S Adams - Acta Crystallographica Section B …, 2019 - journals.iucr.org
The identification of materials for advanced energy-storage systems is still mostly based on
experimental trial and error. Increasingly, computational tools are sought to accelerate …

[PDF][PDF] Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen

OC Gagné, FC Hawthorne - Acta Crystallographica Section B …, 2015 - journals.iucr.org
Published two-body bond-valence parameters for cation–oxygen bonds have been
evaluated via the root mean-square deviation (RMSD) from the valence-sum rule for 128 …

[BOEK][B] The chemical bond in inorganic chemistry: the bond valence model

ID Brown - 2016 - books.google.com
The bond valence model, a description of acid-base bonding, is widely used for analysing
and modelling the structures and properties of solids and liquids. Unlike other models of …

[HTML][HTML] On the effective ionic radii for the tin (II) cation

V Sidey - Journal of Physics and Chemistry of Solids, 2022 - Elsevier
Based on the bond valence (s)–bond length (d) correlation curve accurately approximated
for the Sn 2+/F− ion pair using the equation s= exp [(r 0–d)/b](where the optimized bond …

The Crystal Structure of Pb10(PO4)6O Revisited: The Evidence of Superstructure

SV Krivovichev, G Engel - Crystals, 2023 - mdpi.com
The crystal structure of Pb10 (PO4) 6O, the proposed matrix for the potential room-
temperature superconductor LK-99, Pb10− xCux (PO4) 6O (x= 0.9–1.0), has been …

Revised values of the bond-valence parameters for TeIV—O, TeVI—O and TeIV—Cl

SJ Mills, AG Christy - Acta Crystallographica Section B: Structural …, 2013 - journals.iucr.org
Bond-valence parameters r0 and b have been re-determined for TeIV—O: r0= 1.9605 Å, b=
0.41; TeVI—O: r0= 1.921 Å, b= 0.56; and TeIV—Cl: r0= 2.3115 Å, b= 0.555. Bond distance …

XRD, NMR, FT-IR and DFT structural characterization of a novel organic-inorganic hybrid perovskite-type hexabromotellurate material

M Fizer, M Slivka, V Sidey, V Baumer… - Journal of Molecular …, 2021 - Elsevier
The synthesis of a new hexabromotellurate of triazole ring-containing amino acid is
described. XRD, NMR and DFT analysis of the structure of protonated [(5-amino-4-phenyl-4 …

Crystal chemistry of lead oxide phosphates: crystal structures of Pb4O(PO4)2, Pb8O5(PO4)2 and Pb10(PO4)6O

SV Krivovichev, PC Burns - Zeitschrift für Kristallographie-Crystalline …, 2003 - degruyter.com
Crystals of three Pb oxide phosphates, Pb4O (PO4) 2, Pb8O5 (PO4) 2 and Pb10 (PO4) 6O,
were synthesized from mixtures of PbO and NH4H2PO4 heated to 950° C. The crystal …