Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …
energy is a long-standing challenge in both fundamental science and industry. In recent …
Bimetallic cooperation across the periodic table
J Campos - Nature Reviews Chemistry, 2020 - nature.com
Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …
dominated by mononuclear transition-metal complexes. The catalytic performance and …
Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands
J Takaya - Chemical Science, 2021 - pubs.rsc.org
Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …
Atomic design of carbon-based dual-metal site catalysts for energy applications
H Shang, D Liu - Nano Research, 2023 - Springer
Carbon-based dual-metal sites catalysts (DMSCs) have emerged as a new frontier in the
field of sustainable energy due to their unique coordination environments, electronic …
field of sustainable energy due to their unique coordination environments, electronic …
Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms
T Komuro, Y Nakajima, J Takaya… - Coordination Chemistry …, 2022 - Elsevier
Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …
Rare-earth supported nickel catalysts for alkyne semihydrogenation: chemo-and regioselectivity impacted by the Lewis acidity and size of the support
BL Ramirez, CC Lu - Journal of the American Chemical Society, 2020 - ACS Publications
Bimetallic catalysts of nickel (0) with a trivalent rare-earth ion or Ga (III), NiML3 (where L is
[iPr2PCH2NPh]−, and M is Sc, Y, La, Lu, or Ga), were investigated for the selective …
[iPr2PCH2NPh]−, and M is Sc, Y, La, Lu, or Ga), were investigated for the selective …
Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction
The generation of fuels and value-added chemicals from carbon dioxide (CO2) using
electrocatalysis is a promising approach to the eventual large-scale utilization of intermittent …
electrocatalysis is a promising approach to the eventual large-scale utilization of intermittent …
Carbon dioxide hydrogenation to formate catalyzed by a bench-stable, non-pincer-type Mn (I) alkylcarbonyl complex
The catalytic reduction of carbon dioxide is a process of growing interest for the use of this
simple and abundant molecule as a renewable building block in C1-chemical synthesis and …
simple and abundant molecule as a renewable building block in C1-chemical synthesis and …
Supported metal pair-site catalysts
Complexes with neighboring metal centers in isolated pairs and their analogues on surfaces
are drawing increasing attention as catalysts. These include molecular homogeneous …
are drawing increasing attention as catalysts. These include molecular homogeneous …