Metal–organic frameworks for the chemical fixation of CO2 into cyclic carbonates

TK Pal, D De, PK Bharadwaj - Coordination Chemistry Reviews, 2020 - Elsevier
Presently, we find a rapid pace of CO 2 emission into the atmosphere causing major
problems facing our planet. If no action is taken, it would have harmful consequences to …

Modular organoboron catalysts enable transformations with unprecedented reactivity

GW Yang, YY Zhang, GP Wu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Electron-deficient boron-based catalysts with metal-free but metallomimetic
characteristics provide a versatile platform for chemical transformations. However, their …

Multifunctional catalysts for ring-opening copolymerizations

CAL Lidston, SM Severson, BA Abel, GW Coates - ACS catalysis, 2022 - ACS Publications
The ring-opening copolymerization (ROCOP) of epoxides with CO2 or cyclic anhydrides is a
versatile route toward synthesizing a wide range of polycarbonate and polyester …

Ni/photoredox-catalyzed enantioselective cross-electrophile coupling of styrene oxides with aryl iodides

SH Lau, MA Borden, TJ Steiman, LS Wang… - Journal of the …, 2021 - ACS Publications
A Ni/photoredox-catalyzed enantioselective reductive coupling of styrene oxides and aryl
iodides is reported. This reaction affords access to enantioenriched 2, 2-diarylalcohols from …

Chiral covalent organic frameworks with high chemical stability for heterogeneous asymmetric catalysis

X Han, Q **a, J Huang, Y Liu, C Tan… - Journal of the American …, 2017 - ACS Publications
Covalent organic frameworks (COFs) featuring chirality, stability, and function are of both
fundamental and practical interest, but are yet challenging to achieve. Here we reported the …

Room Temperature Construction of Vicinal Amino Alcohols via Electroreductive Cross-Coupling of N-Heteroarenes and Carbonyls

M Wang, C Zhang, C Ci, H Jiang… - Journal of the …, 2023 - ACS Publications
Despite the widespread applications of α-hydroxyalkyl cyclic amines, direct and diverse
access to such a class of unique vicinal amino alcohols still remains, to date, a challenge …

Direct and Selective Electrocarboxylation of Styrene Oxides with CO2 for Accessing β‐Hydroxy Acids

K Zhang, BH Ren, XF Liu, LL Wang… - Angewandte …, 2022 - Wiley Online Library
Highly selective and direct electroreductive ring‐opening carboxylation of epoxides with
CO2 in an undivided cell is reported. This reaction shows broad substrate scopes within …

Oxidative cyclization in natural product biosynthesis

MC Tang, Y Zou, K Watanabe, CT Walsh… - Chemical …, 2017 - ACS Publications
Oxidative cyclizations are important transformations that occur widely during natural product
biosynthesis. The transformations from acyclic precursors to cyclized products can afford …

Bimetallic catalysis for C–C and C–X coupling reactions

DR Pye, NP Mankad - Chemical Science, 2017 - pubs.rsc.org
Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Facile Synthesis of Metallosalphen‐Based 2D Conductive Metal‐Organic Frameworks for NO2 Sensing: Metal Coordination Induced Planarization

X Su, Z Zhong, X Yan, T Zhang, C Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
As an emerging class of promising porous materials, the development of two‐dimensional
conductive metal organic frameworks (2D c‐MOFs) is hampered by the few categories and …