In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

The carbonyl moiety is one of the indispensable sub-units in organic synthesis with
significant applications in medicinal as well as materials chemistry. Hence the insertion of a …

This review provides a summary of recently published developments in the field of
nonprecious metal catalysis (NPMC) and highlights the range of synthetic applications …

Although iron catalyzed cross-coupling reactions show extraordinary promise in reducing
the environmental impact of more toxic and scarce transition metals, one of the main …

A transition metal-and organophotocatalyst free synthesis of esters, carboxylic anhydrides
and amides from aldehydes induced by visible-light has been reported. The proposed …

Dilithium amides have been developed as a bespoke and general ligand for iron-catalyzed
Kumada–Tamao–Corriu cross-coupling reactions, their design taking inspiration from …

Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable
products across various facets of chemical research, including pharmaceuticals, organic …

The coupling of organolithium reagents, including strongly hindered examples, at cryogenic
temperatures (as low as− 78° C) has been achieved with high‐reactivity Pd‐NHC catalysts …

Alkylated benzosulfonamides are compounds of high importance in organic synthesis,
including the production of pharmaceuticals, agrochemicals, and plasticizers. We report the …

The first cobalt‐catalyzed cross‐coupling of aryl tosylates with alkyl and aryl Grignard
reagents is reported. The catalytic system uses CoF3 and NHCs (NHC= N‐heterocyclic …