Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis

R Ham, CJ Nielsen, S Pullen, JNH Reek - Chemical Reviews, 2023 - ACS Publications
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …

Strain-release photocatalysis

P Bellotti, F Glorius - Journal of the American Chemical Society, 2023 - ACS Publications
The concept of strain in organic compounds is as old as modern organic chemistry and was
initially introduced to justify the synthetic setbacks along the synthesis of small ring systems …

Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis

F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Metal stereogenicity in asymmetric transition metal catalysis

PS Steinlandt, L Zhang, E Meggers - Chemical Reviews, 2023 - ACS Publications
Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Metallaphotoredox catalysis for sp 3 C–H functionalizations through hydrogen atom transfer (HAT)

J Zhang, M Rue** - Chemical Society Reviews, 2023 - pubs.rsc.org
In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …

Photoinduced copper-catalyzed late-stage azidoarylation of alkenes via arylthianthrenium salts

Y Cai, S Chatterjee, T Ritter - Journal of the American Chemical …, 2023 - ACS Publications
The arylethylamine pharmacophore is conserved across a range of biologically active
natural products and pharmaceuticals, particularly in molecules that act on the central …

The mechanism of visible light-induced C–C cross-coupling by C sp3–H bond activation

B Maity, S Dutta, L Cavallo - Chemical Society Reviews, 2023 - pubs.rsc.org
Csp3–C cross-coupling by activating Csp3–H bonds is a dream reaction for the chemical
community, and visible light-induced transition metal-catalysis under mild reaction …