Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Z Liang, HY Wang, H Zheng, W Zhang… - Chemical Society …, 2021 - pubs.rsc.org
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

Promoting oxygen reduction reaction on atomically dispersed Fe sites via establishing hydrogen bonding with the neighboring P atoms

L Zong, K Fan, P Li, F Lu, B Li… - Advanced Energy …, 2023 - Wiley Online Library
Single atom catalysts (SACs) comprised of nitrogen‐coordinated transition metal (TM–N–C)
moieties show encouraging performance towards the oxygen reduction reaction (ORR) …

Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials

F Franco, C Rettenmaier, HS Jeon… - Chemical Society …, 2020 - pubs.rsc.org
The electrochemical reduction of carbon dioxide (CO2) powered by renewable energy is an
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …

Molecular catalysts with diphosphine ligands containing pendant amines

ES Wiedner, AM Appel, S Raugei, WJ Shaw… - Chemical …, 2022 - ACS Publications
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

MJ Chalkley, MW Drover, JC Peters - Chemical reviews, 2020 - ACS Publications
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …

A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts

T Marshall-Roth, NJ Libretto, AT Wrobel… - Nature …, 2020 - nature.com
Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

C Sandford, MA Edwards, KJ Klunder, DP Hickey… - Chemical …, 2019 - pubs.rsc.org
Monitoring reactive intermediates can provide vital information in the study of synthetic
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …

Oxygen reduction by homogeneous molecular catalysts and electrocatalysts

ML Pegis, CF Wise, DJ Martin, JM Mayer - Chemical Reviews, 2018 - ACS Publications
The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …

Rational design of organic electrocatalysts for hydrogen and oxygen electrocatalytic applications

R Cheng, X He, K Li, B Ran, X Zhang, Y Qin… - Advanced …, 2024 - Wiley Online Library
Efficient electrocatalysts are pivotal for advancing green energy conversion technologies.
Organic electrocatalysts, as cost‐effective alternatives to noble‐metal benchmarks, have …