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Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …
various energy conversion and storage systems. However, their sluggish reaction kinetics …
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
Promoting oxygen reduction reaction on atomically dispersed Fe sites via establishing hydrogen bonding with the neighboring P atoms
Single atom catalysts (SACs) comprised of nitrogen‐coordinated transition metal (TM–N–C)
moieties show encouraging performance towards the oxygen reduction reaction (ORR) …
moieties show encouraging performance towards the oxygen reduction reaction (ORR) …
Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials
The electrochemical reduction of carbon dioxide (CO2) powered by renewable energy is an
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …
Molecular catalysts with diphosphine ligands containing pendant amines
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts
Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …
A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms
Monitoring reactive intermediates can provide vital information in the study of synthetic
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …
Oxygen reduction by homogeneous molecular catalysts and electrocatalysts
ML Pegis, CF Wise, DJ Martin, JM Mayer - Chemical Reviews, 2018 - ACS Publications
The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …
energy technologies. This Review provides a comprehensive report of soluble molecular …
Rational design of organic electrocatalysts for hydrogen and oxygen electrocatalytic applications
R Cheng, X He, K Li, B Ran, X Zhang, Y Qin… - Advanced …, 2024 - Wiley Online Library
Efficient electrocatalysts are pivotal for advancing green energy conversion technologies.
Organic electrocatalysts, as cost‐effective alternatives to noble‐metal benchmarks, have …
Organic electrocatalysts, as cost‐effective alternatives to noble‐metal benchmarks, have …