Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds

B Liu, AM Romine, CZ Rubel, KM Engle… - Chemical reviews, 2021 - ACS Publications
Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Pd-catalyzed regioselective activation of C (sp 2)–H and C (sp 3)–H bonds

W Ali, GA Oliver, DB Werz, D Maiti - Chemical Society Reviews, 2024 - pubs.rsc.org
Differentiating between two highly similar C–H bonds in a given molecule remains a
fundamental challenge in synthetic organic chemistry. Directing group assisted strategies for …

Recent developments with organogermanes: their preparation and application in synthesis and catalysis

T Rogova, E Ahrweiler, MD Schoetz… - Angewandte …, 2024 - Wiley Online Library
Within the sphere of traditional Pd0/PdII cross coupling reactions, organogermanes have
been historically outperformed both in terms of scope and reactivity by more conventional …

Quinoline-based metal complexes: Synthesis and applications

R Kumar, A Thakur, D Chandra, AK Dhiman… - Coordination Chemistry …, 2024 - Elsevier
Quinoline-based metal complexes have gained considerable attention in recent years due
to their applications in various fields, including catalysis, material sciences, and medicinal …

Overcoming the Limitations of γ-and δ-C–H Arylation of Amines through Ligand Development

YQ Chen, Z Wang, Y Wu, SR Wisniewski… - Journal of the …, 2018 - ACS Publications
L, X-Type transient directing groups (TDGs) based on a reversible imine linkage have
emerged as broadly useful tools for C–H activation of ketones and free amines. However …

Chiral transient directing groups in transition-metal-catalyzed enantioselective C–H bond functionalization

MI Lapuh, S Mazeh, T Besset - ACS Catalysis, 2020 - ACS Publications
Transition-metal-catalyzed C–H bond functionalization has known a rapid evolution in the
last years, offering modern strategies for reaching high molecular complexity in a step-and …

Progress and perspectives on directing group-assisted palladium-catalysed C–H functionalisation of amino acids and peptides

S Shabani, Y Wu, HG Ryan, CA Hutton - Chemical Society Reviews, 2021 - pubs.rsc.org
Peptide modifications can unlock a variety of compounds with structural diversity and
abundant biological activity. In nature, peptide modifications, such as functionalisation at the …

Modular access to alkylgermanes via reductive germylative alkylation of activated olefins under nickel catalysis

R Gu, X Feng, M Bao, X Zhang - Nature Communications, 2023 - nature.com
Carbon-introducing difunctionalization of CC double bonds enabled by transition-metal
catalysis is one of most straightforward and efficient strategies to construct CC and CX …