Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance

YN Gong, X Guan, HL Jiang - Coordination Chemistry Reviews, 2023 - Elsevier
Covalent organic frameworks (COFs) are a new class of crystalline porous materials
obtained from covalently attached organic building units. By virtue of the unique …

Reticular framework materials for photocatalytic organic reactions

NY Huang, YT Zheng, D Chen, ZY Chen… - Chemical Society …, 2023 - pubs.rsc.org
Photocatalytic organic reactions, harvesting solar energy to produce high value-added
organic chemicals, have attracted increasing attention as a sustainable approach to address …

Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance

Z Chen, J Wang, M Hao, Y **e, X Liu, H Yang… - Nature …, 2023 - nature.com
Covalent organic frameworks (COFs) represent an emerging class of organic photocatalysts.
However, their complicated structures lead to indeterminacy about photocatalytic active sites …

Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis

Y Qian, Y Han, X Zhang, G Yang, G Zhang… - Nature …, 2023 - nature.com
The strong excitonic effects widely exist in polymer-semiconductors and the large exciton
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …

Tuning local charge distribution in multicomponent covalent organic frameworks for dramatically enhanced photocatalytic uranium extraction

H Yang, M Hao, Y **e, X Liu, Y Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Optimizing the electronic structure of covalent organic framework (COF) photocatalysts is
essential for maximizing photocatalytic activity. Herein, we report an isoreticular family of …

Integrating Enrichment, Reduction, and Oxidation Sites in One System for Artificial Photosynthetic Diluted CO2 Reduction

Y Yang, HY Zhang, Y Wang, LH Shao… - Advanced …, 2023 - Wiley Online Library
Artificial photosynthetic diluted CO2 reduction directly driven by natural sunlight is a
challenging, but promising way to realize carbon‐resources recycling utilization. Herein, a …

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Covalent organic frameworks towards photocatalytic applications: Design principles, achievements, and opportunities

S Liu, M Wang, Y He, Q Cheng, T Qian… - Coordination Chemistry …, 2023 - Elsevier
As a subclass of porous framework materials, covalent organic frameworks (COFs) feature
permanent porosity, long-range order, and rigid backbones, and offer an important material …

Recent advances in the use of covalent organic frameworks as heterogenous photocatalysts in organic synthesis

A López‐Magano, S Daliran, AR Oveisi… - Advanced …, 2023 - Wiley Online Library
Organic photochemistry is intensely developed in the 1980s, in which the nature of excited
electronic states and the energy and electron transfer processes are thoroughly studied and …

Efficient Photocatalytic Hydrogen Evolution by Modulating Excitonic Effects in Ni‐Intercalated Covalent Organic Frameworks

R Shen, X Li, C Qin, P Zhang… - Advanced Energy Materials, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) as appealing platforms have received tremendous
interest in the field of photocatalytic H2 evolution owing to their well‐defined structures and …