Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Supramolecular chirality transfer toward chiral aggregation: asymmetric hierarchical self‐assembly

S Huang, H Yu, Q Li - Advanced Science, 2021 - Wiley Online Library
Self‐assembly, as a typical bottom‐up strategy for the fabrication of functional materials, has
been applied to fabricate chiral materials with subtle chiral nanostructures. The chiral …

Mutual monomer orientation to bias the supramolecular polymerization of [6] helicenes and the resulting circularly polarized light and spin filtering properties

R Rodríguez, C Naranjo, A Kumar… - Journal of the …, 2022 - ACS Publications
We report on the synthesis and self-assembly of 2, 15-and 4, 13-disubstituted carbo [6]
helicenes 1 and 2 bearing 3, 4, 5-tridodecyloxybenzamide groups. The self-assembly of …

Solute–solvent interactions in modern physical organic chemistry: Supramolecular polymers as a muse

MFJ Mabesoone, ARA Palmans… - Journal of the American …, 2020 - ACS Publications
Interactions between solvents and solutes are a cornerstone of physical organic chemistry
and have been the subject of investigations over the last century. In recent years, a renewed …

Porphyrin-based supramolecular polymers

H Lee, H Park, DY Ryu, WD Jang - Chemical Society Reviews, 2023 - pubs.rsc.org
Porphyrin derivatives are ubiquitous in bio-organisms and are associated with proteins that
play important biological roles, such as oxygen transport, photosynthesis, and catalysis …

Supramolecular polymerization: a conceptual expansion for innovative materials

PK Hashim, J Bergueiro, EW Meijer, T Aida - Progress in Polymer Science, 2020 - Elsevier
The research field of supramolecular polymerization has dramatically progressed in the last
three decades, and much deeper insights into its new mechanisms, including kinetic and …

Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

E Weyandt, L Leanza, R Capelli, GM Pavan… - Nature …, 2022 - nature.com
Multi-component systems often display convoluted behavior, pathway complexity and
coupled equilibria. In recent years, several ways to control complex systems by manipulating …

Supramolecular Polymer Polymorphism: Spontaneous Helix–Helicoid Transition through Dislocation of Hydrogen-Bonded π-Rosettes

C Otsuka, S Takahashi, A Isobe, T Saito… - Journal of the …, 2023 - ACS Publications
Polymorphism, a phenomenon whereby disparate self-assembled products can be formed
from identical molecules, has incited interest in the field of supramolecular polymers …

Helical nanostructures: chirality transfer and a photodriven transformation from superhelix to nanokebab

H Jiang, Y Jiang, J Han, L Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
Photosensitive cinnamic acid conjugated glutamides were designed to demonstrate
photocontrolled hierarchical chirality transfer and switching in self‐assembled systems. In …

Helical polymers with dynamic and static macromolecular helicity memory: The power of helicity memory for helical polymer synthesis and applications

E Yashima, K Maeda - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
In this Account, we describe the recent progress in the synthesis and unique features and
functions of helical polymers with a controlled handedness based on the noncovalent …