The founding in 1965 of what is now called the Cambridge Structural Database (CSD) has
reaped dividends in numerous and diverse areas of chemical research. Each of the million …

This survey of metal–metal (MM) bond distances in binuclear complexes of the first row 3d-
block elements reviews experimental and computational research on a wide range of such …

This contribution explains how the topological methods of analysis of the electron density
and related functions such as the electron localization function (ELF) and the electron …

For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have
dominated Coordination and Organometallic Chemistry. At the same time, alternative …

Into the metalloligand Cr [N (o-(NCH2P (i Pr) 2) C6H4) 3](1, CrL) was inserted a second
chromium atom to generate the dichromium complex Cr2L (2), which is a homobimetallic …

The reaction of Fe2 (mes) 4 with the super-bulky amidines and guanidines HL Ar*-R (LAr*-
R=[(Ar* N) 2C (R)]−, Ar*= 2, 6-bis (diphenylmethyl)-4-tert-butylphenyl), R= Me (L Ar*-Me), t …

Previously, we reported the synthesis of Ti [N (o-(NCH2P (i Pr) 2) C6H4) 3] and the Fe–Ti
complex, FeTi [N (o-(NCH2P (i Pr) 2) C6H4) 3], abbreviated as TiL (1), and FeTiL (2) …

A set of trisubstituted guanidine ligands L1H2–L4H2 with general formula (i PrHN) 2CNR
(R= Ph (L1H2), R= 2, 4, 6-Me3C6H2 (L2H2), R= p-BrC6H4 (L3H2), R=(C5H4) Fe (C5H5), Fc …

Recent advances on low valent main group metal chemistry have shown the excellent
potential of heterobimetallic complexes derived from Al (I) to promote cooperative small …

Although the field of metal-to-metal multiple bonding has been considered as mature, it was
recently reinvigorated by the discovery of quintuple bonded dinuclear complexes. Initiated …