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% V Bur index and steric maps: from predictive catalysis to machine learning
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …
atoms or groups of atoms in molecules. They are important in determining the reactivity …
C− H functionalisation for hydrogen isotope exchange
J Atzrodt, V Derdau, WJ Kerr… - Angewandte Chemie …, 2018 - Wiley Online Library
The various applications of hydrogen isotopes (deuterium, D, and tritium, T) in the physical
and life sciences demand a range of methods for their installation in an array of molecular …
and life sciences demand a range of methods for their installation in an array of molecular …
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route
N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …
N-heterocyclic carbenes in late transition metal catalysis
N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
Electronic and steric ligand effects both play major roles in organometallic chemistry and
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …
N‐heterocyclic carbenes: a new concept in organometallic catalysis
WA Herrmann - Angewandte Chemie International Edition, 2002 - Wiley Online Library
N‐Heterocyclic carbenes have become universal ligands in organometallic and inorganic
coordination chemistry. They not only bind to any transition metal, be it in low or high …
coordination chemistry. They not only bind to any transition metal, be it in low or high …
Stability and reactivity of N-heterocyclic carbene complexes
The use of N-heterocyclic carbenes as ligands for transition metals has increased
dramatically in the last few years, spurred on by their remarkable successes in the areas of …
dramatically in the last few years, spurred on by their remarkable successes in the areas of …
SambVca: A Web Application for the Calculation of the Buried Volume of N‐Heterocyclic Carbene Ligands
We present a free web application for the calculation of the buried volume (% VBur) of NHC
ligands. The web application provides a graphic and user‐friendly interface to the SambVca …
ligands. The web application provides a graphic and user‐friendly interface to the SambVca …
Understanding the M (NHC)(NHC= N-heterocyclic carbene) bond
N-heterocyclic carbenes (NHC) is a well established class of new ligands in organometallic
chemistry. Their use as ligands in many reactions catalyzed by transition metal complexes …
chemistry. Their use as ligands in many reactions catalyzed by transition metal complexes …
N-heterocyclic carbene transition metal complexes for catalysis in aqueous media
The last decade has seen an increasing number of reports on the use of NHC–metal
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
complexes for catalysis in water, therefore this review is aimed to introduce the whole …