Polymer brushes: surface-immobilized macromolecules

B Zhao, WJ Brittain - Progress in Polymer Science, 2000 - Elsevier
This article reviews recent literature on polymer brushes with an emphasis on linear polymer
brushes attached to solid substrate surfaces. The following topics are included:(i) theoretical …

Sha** the structure and response of surface-grafted polymer brushes via the molecular weight distribution

JC Conrad, ML Robertson - Jacs Au, 2023 - ACS Publications
Breadth in the molecular weight distribution is an inherent feature of synthetic polymer
systems. While in the past this was typically considered as an unavoidable consequence of …

50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials

WL Chen, R Cordero, H Tran, CK Ober - Macromolecules, 2017 - ACS Publications
Polymer brushes have become a significant focus of polymer research with the need for
straightforward and versatile surface modification. With the development of controlled radical …

Structure and properties of high-density polymer brushes prepared by surface-initiated living radical polymerization

Y Tsujii, K Ohno, S Yamamoto, A Goto… - … -initiated polymerization I, 2006 - Springer
Surface modifications by polymers are becoming increasingly important for various
applications ranging from biotechnology to advanced microelectronics. Recent successful …

Forming biocompatible and nonaggregated nanocrystals in water using amphiphilic polymers

WW Yu, E Chang, JC Falkner, J Zhang… - Journal of the …, 2007 - ACS Publications
High-quality nanocrystals formed in organic solvents can be completely solubilized in water
using amphiphilic copolymers containing poly (ethylene glycol) or PEG. These copolymers …

Surface interaction forces of well-defined, high-density polymer brushes studied by atomic force microscopy. 2. Effect of graft density

S Yamamoto, M Ejaz, Y Tsujii, T Fukuda - Macromolecules, 2000 - ACS Publications
Poly (methyl methacrylate)(PMMA) brushes with the same chain length but different graft
densities were prepared on a silicon substrate by the surface-initiated atom transfer radical …

Nanoscopic interfacial hydrogel viscoelasticity revealed from comparison of macroscopic and microscopic rheology

RF Schmidt, H Kiefer, R Dalgliesh, M Gradzielski… - Nano Letters, 2024 - ACS Publications
Deviations between macrorheological and particle-based microrheological measurements
are often considered to be a nuisance and neglected. We study aqueous poly (ethylene …

Tethered polymer layers

I Szleifer, MA Carignano - Advances in chemical physics, 1996 - books.google.com
166 1. SZLEIFER AND MA CARIGNANO molecules in bulk. The presence of a wall limits the
configurational space of the chains and the two-dimensional anchoring makes the …

Polymer on top: Current limits and future perspectives of quantitatively evaluating surface grafting

L Michalek, L Barner, C Barner‐Kowollik - Advanced Materials, 2018 - Wiley Online Library
Well‐defined polymer strands covalently tethered onto solid substrates determine the
properties of the resulting functional interface. Herein, the current approaches to determine …

Novel neutron reflectometer SOFIA at J-PARC/MLF for in-situ soft-interface characterization

K Mitamura, NL Yamada, H Sagehashi, N Torikai… - Polymer …, 2013 - nature.com
Structural characterization of interfaces composed of soft materials (soft interfaces) helps in
understanding their physical behavior. Neutron reflectometry is one of the most powerful …