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Multiscale and multistep ordering of flow-induced nucleation of polymers
Flow-induced crystallization (FIC) is a typical nonequilibrium phase transition and a core
industry subject for the largest group of commercially useful polymeric materials …
industry subject for the largest group of commercially useful polymeric materials …
Tailoring hydrocarbon polymers and all‐hydrocarbon composites for circular economy
T Hees, F Zhong, M Stürzel… - Macromolecular rapid …, 2019 - Wiley Online Library
The world population will rapidly grow from 7 to 9 billion by 2050 and this will parallel a
surging annual plastics consumption from today's 350 million tons to well beyond 1 billion …
surging annual plastics consumption from today's 350 million tons to well beyond 1 billion …
Control of structural morphology in shear-induced crystallization of polymers
OO Mykhaylyk, P Chambon, C Impradice… - …, 2010 - ACS Publications
Critical examination finds that the longest chains play a catalytic role in the formation of
shish kebabs recruiting other chains into the formation of this morphology. The longest …
shish kebabs recruiting other chains into the formation of this morphology. The longest …
Crystallization and dissolution of flow-induced precursors
We make use of a specially synthesized linear high density polyethylene with a bimodal
molecular weight distribution (MWD) to demonstrate that it is possible to produce a …
molecular weight distribution (MWD) to demonstrate that it is possible to produce a …
Onset of flow-induced crystallization kinetics of highly isotactic polypropylene
Brief intervals of shear prior to a temperature quench accelerate crystallization, resulting in
much smaller spherulites. Crystallization kinetics of five commercial linear isotactic …
much smaller spherulites. Crystallization kinetics of five commercial linear isotactic …
Shear-induced nucleation and morphological evolution for bimodal long chain branched polylactide
The effects of long chain branching on the nucleation density enhancements and
morphological evolution for polylactide (PLA) materials during shear-induced isothermal …
morphological evolution for polylactide (PLA) materials during shear-induced isothermal …
Flow memory and stability of shear-induced nucleation precursors in isotactic polypropylene
The dissolution of flow-induced nucleation precursors in isotactic polypropylene is
investigated indirectly by means of in situ rheo-SAXS measurements. The progress of …
investigated indirectly by means of in situ rheo-SAXS measurements. The progress of …
Understanding flow-induced crystallization in polymers: A perspective on the role of molecular simulations
RS Graham - Journal of Rheology, 2019 - pubs.aip.org
Flow-induced crystallization in polymers is an important problem in both fundamental
polymer science and industrial polymer processing. The key process of flow-induced …
polymer science and industrial polymer processing. The key process of flow-induced …
Coarse-grained simulations of flow-induced nucleation in semicrystalline polymers
We perform kinetic Monte Carlo simulations of flow-induced nucleation in polymer melts with
an algorithm that is tractable even at low undercooling. The configuration of the …
an algorithm that is tractable even at low undercooling. The configuration of the …
[HTML][HTML] How atomic force microscopy has contributed to our understanding of polymer crystallization
JK Hobbs, OE Farrance, L Kailas - Polymer, 2009 - Elsevier
Over the past two decades atomic force microscopy (AFM) has become one of the most
frequently used tools for studying polymer crystallization. The combination of high resolution …
frequently used tools for studying polymer crystallization. The combination of high resolution …