Nanostructured ceria-based materials: synthesis, properties, and applications
The controllable synthesis of nanostructured CeO2-based materials is an imperative issue
for environment-and energy-related applications. In this review, we present the recent …
for environment-and energy-related applications. In this review, we present the recent …
Oxygen defects and surface chemistry of ceria: quantum chemical studies compared to experiment
As one of the most significant rare earth oxides, ceria (CeO 2) has attracted much interest
over the past decades. In catalysis, 1, 2 CeO2 serves as a widely used support material and …
over the past decades. In catalysis, 1, 2 CeO2 serves as a widely used support material and …
Structure of the catalytically active copper–ceria interfacial perimeter
A Chen, X Yu, Y Zhou, S Miao, Y Li, S Kuld… - Nature Catalysis, 2019 - nature.com
Cu/CeO2 catalysts are highly active for the low-temperature water–gas shift—a core reaction
in syngas chemistry for tuning the H2/CO/CO2 proportions in feed streams—but the direct …
in syngas chemistry for tuning the H2/CO/CO2 proportions in feed streams—but the direct …
Catalysis by doped oxides
Metal oxide catalysts have numerous industrial applications. 1− 7 In addition, oxides
catalyze many important reactions whose conversion or selectivity is too low to be …
catalyze many important reactions whose conversion or selectivity is too low to be …
Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges
Defects at transition metal (TM) and rare earth (RE) oxide surfaces, neutral oxygen
vacancies in particular, play a major role in a variety of technological applications. This is the …
vacancies in particular, play a major role in a variety of technological applications. This is the …
Hubbard‐corrected DFT energy functionals: The LDA+ U description of correlated systems
The aim of this review article is to assess the descriptive capabilities of the Hubbard‐rooted
LDA+ U method and to clarify the conditions under which it can be expected to be most …
LDA+ U method and to clarify the conditions under which it can be expected to be most …
Pt atomic single-layer catalyst embedded in defect-enriched ceria for efficient CO oxidation
The local coordination structure of metal sites essentially determines the performance of
supported metal catalysts. Using a surface defect enrichment strategy, we successfully …
supported metal catalysts. Using a surface defect enrichment strategy, we successfully …
Photosensitized peroxidase mimicry at the hierarchical 0D/2D heterojunction‐like quasi metal‐organic framework interface for boosting biocatalytic disinfection
Metal‐organic frameworks (MOFs) are a versatile toolbox for the bioinspired design of
nanozymes for antibacterial applications and beyond, however, designing a nanozyme by …
nanozymes for antibacterial applications and beyond, however, designing a nanozyme by …
Creating single-atom Pt-ceria catalysts by surface step decoration
F Dvořák, M Farnesi Camellone, A Tovt… - Nature …, 2016 - nature.com
Single-atom catalysts maximize the utilization of supported precious metals by exposing
every single metal atom to reactants. To avoid sintering and deactivation at realistic reaction …
every single metal atom to reactants. To avoid sintering and deactivation at realistic reaction …
High Catalytic Activity and Chemoselectivity of Sub-nanometric Pd Clusters on Porous Nanorods of CeO2 for Hydrogenation of Nitroarenes
Sub-nanometric Pd clusters on porous nanorods of CeO2 (PN-CeO2) with a high Pd
dispersion of 73.6% exhibit the highest catalytic activity and best chemoselectivity for …
dispersion of 73.6% exhibit the highest catalytic activity and best chemoselectivity for …