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Recognition of amino acids by functionalized calixarenes
The calixarenic receptors exhibit remarkable host–guest properties towards biologically
relevant guests. Aspects of complex formation reactions between both native and …
relevant guests. Aspects of complex formation reactions between both native and …
Chiral analysis of pharmaceuticals using NMR spectroscopy: A review
V Kumar Vashistha - Asian journal of organic chemistry, 2022 - Wiley Online Library
Chirality recognition of pharmaceutical products plays a significant part in asymmetric
synthesis, stereoselective catalysis, supramolecular chemistry, and the development of new …
synthesis, stereoselective catalysis, supramolecular chemistry, and the development of new …
Calixarene-based chiral phase-transfer catalysts derived from cinchona alkaloids for enantioselective synthesis of α-amino acids
The synthesis of the first calixarene-based chiral phase-transfer catalysts derived from
cinchona alkaloids has been achieved in two steps from p-tert-butylcalix [4] arene. The …
cinchona alkaloids has been achieved in two steps from p-tert-butylcalix [4] arene. The …
Chiral calix [4] azacrowns for enantiomeric recognition of amino acid derivatives
In this study the synthesis of novel chiral calix [4] azacrown derivatives has been reported.
The enantioselectivity of chiral receptors was investigated by using UV–vis spectroscopy. All …
The enantioselectivity of chiral receptors was investigated by using UV–vis spectroscopy. All …
Synthesis of chiral calix [4] arenes bearing aminonaphthol moieties and their use in the enantiomeric recognition of carboxylic acids
Two armed chiral calix [4] arenes 8–16 functionalized at the lower rim with chiral
aminonaphthol units have been prepared and the structures of these receptors …
aminonaphthol units have been prepared and the structures of these receptors …
Chiral analysis by NMR spectroscopy: chiral solvating agents
F Balzano, G Uccello-Barretta, F Aiello - Chiral analysis, 2018 - Elsevier
This chapter will focus on the use of chiral solvating agents (CSAs) for the detection and
quantification of enantiomeric substrates by nuclear magnetic resonance spectroscopy, with …
quantification of enantiomeric substrates by nuclear magnetic resonance spectroscopy, with …
Amino alcohol based chiral solvating agents: synthesis and applications in the NMR enantiodiscrimination of carboxylic acids
Four optically active amino alcohols were synthesized via the ring opening of (R)-N-(2, 3-
epoxypropyl) phthalimide with (R)-2-phenyl glycinol,(1R, 2S)-cis-1-amino-2-indanol,(R)-2 …
epoxypropyl) phthalimide with (R)-2-phenyl glycinol,(1R, 2S)-cis-1-amino-2-indanol,(R)-2 …
[PDF][PDF] Chiral calixarenes
Calixarenes, obtained in the condensation reaction of formaldehyde and p-substituted
phenols, are often referred to as the third generation of supramolecular receptors after crown …
phenols, are often referred to as the third generation of supramolecular receptors after crown …
Calixarenes and calix [4] resorcinarenes as chiral NMR solvating agents
TJ Wenzel - Journal of Inclusion Phenomena and Macrocyclic …, 2014 - Springer
Abstract Calixarenes (CAs) and calix [4] resorcinarenes are cavity compounds, chiral
analogues of which have the potential to be used as reagents for the differentiation of …
analogues of which have the potential to be used as reagents for the differentiation of …
Enantiodiscrimination of carboxylic acids using the diphenylprolinol NMR chiral solvating agents
G Li, J Cao, W Zong, X Lei, R Tan - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Enantiopure diphenylprolinols were synthesized from a commercially available starting
material. The utility of 1H NMR spectroscopy for the differentiation of enantiomers using …
material. The utility of 1H NMR spectroscopy for the differentiation of enantiomers using …