Crystallization in thin films of polymer glasses: The role of free surfaces, solid interfaces and their competition
Polymer coatings of nanometric thickness are about to enter in everyday life as part of a
wide range of applications such as protective layers, stimuli-responsive membranes or as …
wide range of applications such as protective layers, stimuli-responsive membranes or as …
Relaxation behavior of polymer thin films: Effects of free surface, buried interface, and geometrical confinement
The glass transition temperature (T g) of polymer thin films, one of the most important
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …
Surface dynamics of glasses
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …
Dynamics gradient of polymer chains near a solid interface
HK Nguyen, S Sugimoto, A Konomi, M Inutsuka… - ACS Macro …, 2019 - ACS Publications
The relaxation dynamics of polyisoprene (PI) and nitrile butadiene rubber (NBR) chains at
the SiO2 interface were directly probed as a function of distance from the SiO2 surface using …
the SiO2 interface were directly probed as a function of distance from the SiO2 surface using …
Interface structure and dynamics in polymer‐nanoparticle hybrids: a review on molecular mechanisms underlying the improved interfaces
MA Sattar - ChemistrySelect, 2021 - Wiley Online Library
In a nano‐assembly of soft polymer chains and hard filler nanoparticles (NPs), the
intermolecular interactions at the polymer‐filler interface lead to variations in viscoelastic …
intermolecular interactions at the polymer‐filler interface lead to variations in viscoelastic …
Aggregation states, thermal molecular motion and carrier properties in functional polymer thin films
D Kawaguchi - Polymer Journal, 2023 - nature.com
Functional polymers, such as semiconducting polymers and polyelectrolytes, play an
essential role in polymeric devices due to their electronic properties. The performance of the …
essential role in polymeric devices due to their electronic properties. The performance of the …
Role of Interface Structure and Chain Dynamics on the Diverging Glass Transition Behavior of SSBR-SiO2-PIL Elastomers
MA Sattar, A Patnaik - ACS omega, 2020 - ACS Publications
Intermolecular interactions between the constituents of a polymer nanocomposite at the
polymer–particle interface strongly affect the segmental mobility of polymer chains …
polymer–particle interface strongly affect the segmental mobility of polymer chains …
Absolute molecular structure of the polystyrene at the buried polystyrene/silica interface and its relationship to dewetting during annealing
Dewetting is a common phenomenon observed from polymer thin films under stimuli, such
as annealing, which directly affects the applications of polymer thin films. A key to …
as annealing, which directly affects the applications of polymer thin films. A key to …
Design Principles of Interfacial Dynamic Bonds in Self‐Healing Materials: What are the Parameters?
MA Sattar, A Patnaik - Chemistry–An Asian Journal, 2020 - Wiley Online Library
Polymers and polymer nanocomposites (PNCs) are extensively used in daily life. However,
the growing requirement of advanced PNCs laid persistent environmental issues due to …
the growing requirement of advanced PNCs laid persistent environmental issues due to …
Local orientation of chains at crystal/amorphous interfaces buried in isotactic polypropylene thin films
D Kawaguchi, K Yamamoto, T Abe, N Jiang… - Physical Chemistry …, 2021 - pubs.rsc.org
A better understanding of the aggregation states of polymer chains in thin films is of pivotal
importance for develo** thin film polymer devices in addition to its inherent scientific …
importance for develo** thin film polymer devices in addition to its inherent scientific …